Novel benzylsulfonylureas and arylsulfamoylureas N-[(substituted pyrimidin-2-yl)aminocarbonyl]-1-oxo-fused benzyl-7-methanesulfonamides useful as herbicides and plant growth regulants

ABSTRACT

Benzylsulfonylureas and arylsulfamoylureas are useful as pre-emergent and post-emergent herbicides and as plant growth regulants.

RELATED APPLICATION

This application is a continuation-in-part of copending application Ser.No. 585,170, filed Mar. 1, 1984 now abandoned.

BACKGROUND OF THE INVENTION

European Patent Application No. 51,466, published May 12, 1982,discloses compounds of the formula ##STR1## where W is a substitutedbenzyl; Z is CH or N; X is CH₃, OCH₃, or Cl; and Y is CH₃, C₂ H₅, OCH₃,OC₂ H₅, CH₂ OCH₃, NH₂, NHCH₃, or N(CH₃)₂. The compounds are disclosed tohave pre- and post-emergent herbicidal activity and to be useful asplant growth regulators.

European Patent Application No. 71,441, published Feb. 9, 1983,discloses compounds of the formula ##STR2## where Z is CH or N; X is CH₃or OCH₃ ; Y is Cl, CH₃, OCH₃, OC₂ H₅, CH₂ OCH₃, NH₂, NHCH₃, N(CH₃)₂,CH(OCH₃)₂, or ##STR3## and L is ##STR4## where R₁ is H or C₁ -C₃ alkyl;R₂ is H or CH₃, R₅ is H, CH₃, OCH₃, Cl, Br, NO₂, CO₂ R₇, SO₂ R₈, OSO₂R₉, SO₂ NR₁₀ R₁₁ ; R₆ is H or C₁ -C₃ alkyl; R₆ ' is H or CH₃ ; Q is O,S, or SO₂ ; and Q₁ is CR₃ R₄ or O.

Utility as a pre- or post-emergent herbicide and as a plant growthregulant is disclosed.

European Patent Application No. 79,683, published May 25, 1983,discloses compounds, useful as herbicides or plant growth regulants, ofthe formula ##STR5## where Z is CH or N; X and Y are as in EuropeanApplication No. 51,466 (described above) and J is ##STR6## Q is O, S orSO₂ ; R is H or CH₃ ;

R₁ is H, CH₃, OCH₃, Cl, Br, CO₂ R₅, SO₂ R₆, OSO₂ R₇ or SO₂ NR₈ R₉ ;

R₂ and R₃ are independently H or C₁ -C₃ alkyl;

R₄ is H or CH₃ ;

R₅ is C₁ -C₃ alkyl, CH₂ CH═CH₂, CH₂ CH₂ OCH₃ or CH₂ CH₂ Cl;

R₆ is C₁ -C₃ alkyl;

R₇ is C₁ -C₃ alkyl or CF₃ ; and

R₈ and R₉ are independently C₁ -C₂ alkyl.

SUMMARY OF THE INVENTION

The present invention relates to novel compounds of Formula I,agriculturally suitable compositions containing them, and theirmethod-of-use as pre-emergent or post-emergent herbicides or plantgrowth regulants. ##STR7## wherein J is ##STR8## n is 0 or 1; L is CH₂or O;

Q is CH₂ or O;

Q₁ is O, S or SO₂ ;

Q₂ is O or S;

R is H or CH₃ ;

R₁ is H, F, Cl, Br, CH₃ or OCH₃ ;

R₂ is H or C₁ -C₃ alkyl;

R₃ is H or CH₃ ;

R₄ is H or CH₃ ;

R₅ is H, CH₃ or C₂ H₅ ;

R₆ is H or CH₃ ;

R₇ is H or CH₃ ;

R₈ is F, Cl, Br, OCH₃, SCH₃, SO₂ CH₃, CO₂ CH₃, SO₂ N(CH₃)₂ or OSO₂ CH₃ ;

R₉ is H, OH, C₁ -C₆ alkyl, C₁ -C₆ haloalkyl, C₁ -C₆ alkoxyalkyl, C₃ -C₆alkenyl, C₃ -C₆ alkynyl, C₁ -C₆ alkoxy, phenyl, C₃ -C₆ cycloalkyl, C₄-C₇ cycloalkylalkyl, C₁ -C₆ alkylcarbonyl, C₁ -C₆ alkoxycarbonyl,benzyl, C₃ -C₄ haloalkenyl, C₃ -C₆ haloalkynyl, C₃ -C₆alkylcarbonylalkyl, C₃ -C₆ alkoxycarbonylalkyl or C₁ -C₄ cyanoalkyl;

A is ##STR9## X is CH₃, OCH₃, Cl, Br, OCH₂ CF₃ or OCF₂ H; Y is C₁ -C₃alkyl, CH₂ F, cyclopropyl, C.tbd.CH, OCH₃, OC₂ H₅, CH₂ OCH₃, NH₂, NHCH₃,N(CH₃)₂, OCH₂ CH₂ F, CF₃, SCH₃, OCH₂ CH=CH₂, OCH₂ C.tbd.CH, OCH₂ CH₂OCH₃, CR(OCH₃)₂, ##STR10## CR(OCH₂ CH₃)₂ or OCF₂ H; Z is CH or N;

X₁ is CH₃, OCH₃, OC₂ H₅ or OCF₂ H;

Y₁ is O or CH₂ ;

X₂ is CH₃, C₂ H₅ or CH₂ CF₃ ;

Y₂ is OCH₃, OC₂ H₅, SCH₃, SC₂ H₅, OCF₂ H, SCF₂ H, CH₃ or CH₂ CH₃ ;

X₃ is CH₃ or OCH₃ ; and

Y₃ is H or CH₃ ;

provided that

(1) when X is Cl or Br, then Z is CH and Y is OCH₃, OC₂ H₅, NHCH₃,N(CH₃)₂ or OCF₂ H; and

(2) when X or Y is OCF₂ H, then Z is CH.

Compounds of formula I that are preferred for reasons of their higherherbicidal activity, greater plant growth regulant activity or morefavorable ease of synthesis are:

(1) Compounds in which A is A-1.

(2) Compounds of the scope of (1) where Y is CH₃, C₂ H₅, OCH₃, OC₂ H₅,CH₂ OCH₃, CH₂ F or CF₃ ; and L is CH₂.

(3) Compounds of the scope of (2) where J is J₁, J₃, J₇, J₈, J₁₅ or J₁₆.

(4) Compounds of the scope of (3) where R is H; R₁ is H; and X is CH₃ orOCH₃.

Compounds that are specifically preferred are

1,3-dihydro-N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-1-oxo-benzo[c]furan-7-methanesulfonamide;

1,3-dihydro-N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocarbonyl]-1-oxo-benzo[c]furan-7-methanesulfonamide;

N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-2,3-dihydro-2-methyl-benzo[B]thiophene-7-methanesulfonamide-1,1-dioxide;and

N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocarbonyl]-2-methyl-benzo[B]thiophene-7-methanesulfonamide-1,1-dioxide.

DETAILED DESCRIPTION OF THE INVENTION Synthesis

The compounds of Formula I can be prepared as indicated by one or moreof the methods shown below in Equations 1, 2, 3, and 4.

Equation 1 depicts the reaction of sulfonyl isocyanates of Formula II,where J is other than J₁₉, with the appropriate heterocyclic amines,III, to give the desired products of Formula Ia.

EQUATION 1 ##STR11## wherein J, X, Y and Z are as previously defined, R₂is C₁ -C₃ alkyl and R₉ is other than H or OH.

The reaction of Equation 1 is best carried out in an inert aproticsolvent such as methylene chloride, tetrahydrofuran, or acetonitrile ata temperature between 20° and 80° C. A catalytic amount of1,4-diazabicyclo[2,2,2-octane (DABCO) may be used to accelerate thereaction. In cases in which the products are insoluble in the reactionsolvent, they may be isolated by simple filtration. When the productsare soluble, they may be isolated by evaporation of the solvent andtrituration of the residue with solvents such as 1-chlorobutane, diethylether, or methanol, and filtration.

Compounds of Formula Ib, where J is other than J₃, J₄, J₅, J₆, J₈, J₉,and J₁₂, and where L is --CH₂ --, can be prepared as shown in Equation 2by treating sulfonamides of Formula IV with the methyl ester of apyrimidine or triazinecarbamic acid of Formula V in the presence of anequimolar quantity of trimethylaluminum.

EQUATION 2 ##STR12## wherein X, Y and Z are as previously defined and Jis as defined above.

The reaction of Equation 2 is best carried out at temperaturesbetween25° and 83° C. in a solvent such as methylene chloride or1,2-dichloroethane for 12 to 96 hours under an inert atmosphere, astaught in European Patent No. 84,244 (issued July 27, 1983). The methylcarbamates, V, can be conveniently synthesized by treatment of thecorresponding heterocyclic amines of Formula III with dimethyl carbonateor methyl chloroformate in the presence of a base such as sodium hydrideor pyridine.

Alternatively, compounds of Formula Ic, where J is other than J₅, J₆,J₁₀, and J₁₁, and where L is --CH₂ --, can be prepared as shown below inEquation 3 by the reaction of sulfonamides of Formula IV with the phenylester of the appropriate carbamic acid, VI, in the presence of anequimolar quantity of a tertiary amine base such as1,5-diazabicyclo[5.4.0]undec-5-ene (DBU).

EQUATION 3 ##STR13## wherein J, X, Y and Z are as previously defined.

The reaction shown in Equation 3 is carried out at about 23° C. in asuitable solvent such as dioxane or acetonitrile. Aqueous acid work-upaffords the desired products as described in European Patent ApplicationNo. 70,804 (published Jan. 26, 1983). The phenyl carbamates, VI, can besynthesized by treating the corresponding heterocyclic amines of FormulaIII with diphenyl carbonate or phenyl chloroformate in the presence of abase such as sodium hydride or pyridine.

Compounds of Formula Id, where J is other than J₁₅, J₁₇, and J₁₉, andwhere L is 0, can be prepared as shown below in Equation 4. Theintermediate chlorosulfonylurea of Formula VII is formed by treatment ofthe corresponding heterocyclic amine, III, with commercially availablechlorosulfonyl isocyanate and is then allowed to react with anappropriate phenol of Formula VIII.

EQUATION 4 ##STR14## wherein J, X, Y and Z are as previously defined.

The reaction shown in Equation 4 is best carried out according to themethods taught in U.S. Pat. No. 4,391,976.

Sulfonyl isocyanates of Formula IIa, where J is other than J₁₉, and R₂is C₁ -C₃ alkyl, R₉ is other than hydrogen and hydroxy, and where L is--CH₂ --, can be prepared as shown in Equation 5 by the reaction of thecorresponding sulfonamides of general structure IV with phosgene in thepresence of n-butyl isocyanate and a catalytic amount of1,4-diazabicyclo-[2.2.2]octane (DABCO). Alternatively, the sulfonylisocyanates, IIa, may be prepared via phosgenation of the appropriaten-butylureas of Formula IX as represented in Equation 6.

Equation 5 ##STR15## wherein J is as previously defined.

The reaction shown in Equation 5 is best carried out according to theprocedure described in U.S. Pat. No. 4,238,621.

EQUATION 6 ##STR16## wherein J is as previously defined.

The compounds of Formula IX are conveniently prepared by stirring amixture of the appropriate sulfonamides, IV, anhydrous potassiumcarbonate, and n-butyl isocyanate in acetone or methyl ethyl ketone at25° to 80° C. until all of the isocyanate has reacted. The products areisolated by quenching in dilute mineral acid and recrystallizing thesolid product. The compounds IX are treated with phosgene and acatalytic amount of DABCO in refluxing xylene or chlorobenzene in amanner analogous to that described in Equation 5.

Another method for the preparation of sulfonyl isocyanates IIa is shownin Equation 7. Treatment of sulfonamides of Formula IV with thionylchloride gives intermediate N-sulfinylsulfonamides, X, which affordsulfonyl isocyanates of Formula IIa upon exposure to phosgene in thepresence of a catalytic amount of pyridine.

EQUATION 7 ##STR17## wherein J is as previously defined.

The reaction of Equation 7 can best be performed according to theprocedure of H. Ulrich. B. Tucker, and A. Sayigh, J. Org. Chem., 34,3200 (1969).

Sulfonyl isocyanates of Formula IIb, where J is other than J₁₅, J₁₇ orJ₁₉, R₂ is C₁ -C₃ alkyl, R₉ is other than hydrogen and hydroxy, and L is0, can be most easily prepared as shown below in Equation 8 by thereaction of appropriately substituted phenols of Formula VIII withchlorosulfonyl isocyanate. This procedure is taught in U.S. Pat. Nos.4,191,553 and 4,394,153, and by Lohaus in Chem. Ber., 105, 2791 (1972).

EQUATION 8 ##STR18## wherein J is as previously defined.

The requisite sulfonamides of Formula IVa can be synthesized from theappropriately substituted benzyl chlorides or benzyl bromides, XI, bythe three-step sequence of reactions outlined below in Equation 9.

EQUATION 9 ##STR19## wherein X' is chlorine or bromine;

J is J₁, J₂, J₃, J₁₃, J₁₄, J₁₅, J₁₆, J₂₀, or J₂₁ ;

L is --CH₂ --; and

when J is J₁₅ or J₁₆, Q₁ is SO₂.

EQUATION 9(a)

The conversion of alkyl halides to isothiouronium salts is wellprecedented in the literature. For relevant examples, see T. B. Johnsonand J. M. Sprague, J. Am. Chem. Soc., 58, 1348 (1936); 59, 1837 and 2439(1937); 61, 176 (1939). In a typical procedure, a benzyl halide ofFormula XI is treated with thiourea in a suitable solvent such asethanol or tetrahydrofuran. Temperatures of 40°-80° C. over one-half to4 hours are typically required to complete the reaction. The productsalts, XII, are isolated by cooling and filtration or by concentrationto remove the solvent. The salts, XII, are generally sufficiently pureto be carried on directly to step (9b) without further purification.

EQUATION 9(b)

The oxidative chlorination of isothiouronium salts to afford sulfonylchlorides is most conveniently effected according to the procedure ofJohnson as described in J. Am. Chem. Soc., 61, 2548 (1939). Thus, theappropriate isothiouronium salts, XII, are suspended in aqueous aceticacid and treated with at least three equivalents of chlorine attemperatures between 0° and 20° C. The product sulfonyl chlorides ofFormula XIII are isolated by filtration or extraction into methylenechloride followed by drying and evaporation of the solvent. No furtherpurification of the sulfonyl chlorides is necessary.

EQUATION 9(c)

In Equation (9c), the sulfonyl chlorides of Formula XIII are suspendedin an aprotic solvent such as diethyl ether, 1-chlorobutane, methylenechloride, or tetrahydrofuran and contacted with an excess of anhydrousammonia at a temperature of 0° to 25° C. The product sulfonamides ofFormula IVa are isolated by filtration and washing with water to removethe byproduct ammonium chloride, and concentrating the organic solution.Frequently, the crude sulfonamides may be used directly to prepare thesulfonyl isocyanates of Formula II. However, they may also be purifiedfirst by recrystallization from a suitable organic solvent such asethanol, acetonitrile or chloroform.

Sulfonamides of Formula IVb can be prepared starting from theappropriate benzyl halides of Formula XI by the three-step sequence ofreactions shown below in Equation 10.

EQUATION 10 ##STR20## wherein X' is chlorine or bromine;

J is other than J₂, J₅, J₆, J₁₀ or J₁₁ ; and L is --CH₂ --.

EQUATION 10(a)

The displacement reaction of Equation 10(a) is best carried out bytreating the benzyl halides XI with sodium sulfite at reflux temperaturefor 3 to 12 hours in water or aqueous methanol. The solution is cooledand the solvent removed in vacuo to give a residue which is washed withmethanol or ethyl acetate and filtered. Evaporation of the filtrateaffords the sodium sulfonate salts which is typically carried directlyon to the next step. For examples of this reaction, see Reed and Tarter,J. Am. Chem. Soc., 57, 571 (1935); and Latimer and Bost. J. Org. Chem.,5, 24 (1940).

EQUATION 10(b)

The reaction shown in Equation 10(b) can be effected by warming amixture of the dried salts of Formula XIV with phosphorous pentachlorideor phosphorous oxychloride according to the procedure of S. Hazlet, J.Am. Chem. Soc., 59, 287 (1937) or O. Billeter, Ber. Deut. Chem. Ges.,38, 2018 (1935). The product sulfonyl chlorides, XIII, are isolatedeither by distillation from the crude reaction mixture or by extractioninto a suitable solvent such as methylene chloride or 1-chlorobutane.

EQUATION 10(c)

The amination reaction of Equation 10(c) is carried out as describedabove for Equation 9(c).

Benzyl halides of Formulas XIa and XIb (X'=Br or Cl) may be prepared asshown below in Equation 11 by treatment of the appropriately substitutedtoluene derivatives, XV, with either N-bromosuccinimide (NBS) orN-chlorosuccinimide (NCS).

EQUATION 11 ##STR21## wherein X' is chlorine or bromine;

J is J₇, J₈, J₉, J₁₂, J₁₇, J₁₈, J₁₉, J₂₀ or J₂₁ ;

L is --CH₂ --;

R₁ is H, F, Cl, Br or OCH₃ ; and when J is J₈ or J₁₂, R₃ is H, and whenJ is J₁₇, R₃ and R₄ are H.

The reaction of Equation 11 can be most conveniently carried out byheating a solution of the toluene derivatives, XV, and eitherN-bromosuccinimide or N-chlorosuccinimide in a suitable solvent such ascarbon tetrachloride at reflux temperature. A free radical catalyst suchas azoisobutyronitrile or benzoyl peroxide is usually employed toinitiate the reaction. When the reaction is complete, the cooledsolution is filtered to remove the by-product succinimide and thefiltrate concentrated in vacuo. The benzyl halides of Formulas XIa andXIb are often obtained in a sufficiently pure state for furthertransformation.

An alternate method for the preparation of benzyl chlorides of FormulaXIb starting from the appropriate benzyl alcohols of Formula XVI isoutlined below in Equation 12.

EQUATION 12 ##STR22## wherein X' is chlorine;

J is other than J₅, J₆, J₁₀ or J₁₁ ; and

L is --CH₂ --.

There exists a wide variety of well known methods for converting alkylalcohols to the corresponding chlorides. One of the most commonprocedures involves treatment of the alcohols with thionyl chlorideeither alone or in the presence of a suitable base such as pyridine. Forrelevant examples, see the following references: H. Gilman and J. E.Kirby, J. Am. Chem. Soc., 51, 3475 (1929); H. Gilman and A. P. Hewlett,Rec. Trav. Chim., 51, 93 (1932); or M. S. Newman, J. Am. Chem. Soc., 62,2295 (1940).

The requisite benzyl alcohols of Formula XVI (shown below in Equation 13for the specific example of J=J₁₆) can be synthesized by reduction ofthe appropriately substituted benzoic acid derivatives of Formula XVIIwith diborane in a solvent such as tetrahydrofuran.

EQUATION 13 ##STR23## wherein R₁, R₃, R₄ and Q₁ are as previouslydefined.

Although the reaction of Equation 13 is shown specifically for J=J₁₆,this reduction is applicable to ring systems J₁, J₂, J₃, J₄, J₁₃, J₁₄,J₁₅, J₁₈, J₁₉, J₂₀ and J₂₁ where L is --CH₂ --. For a description of theuse of diborane for reduction of benzoic acid derivatives, see H. C.Brown, J. Org. Chem., 38, 2786 (1973).

Alternatively, benzyl alcohols of Formula XVI (shown below in Equation14 for the specific example of J=J₁₆) can be synthesized by reduction ofthe appropriately substituted benzaldehyde derivatives of Formula XVIIIwith sodium borohydride in a solvent such as ethanol.

EQUATION 14 ##STR24## wherein R₁, R₃, R₄ and Q₁ are as previouslydefined.

Although the reaction of Equation 14 is shown specifically for J=J₁₆,this reduction is applicable to ring systems J₁, J₂, J₃, J₄, J₇, J₈, J₉,J₁₂, J₁₃, J₁₄, J₁₅, J₁₇, J₁₈, J₁₉, J₂₀ and J₂₁ where L is --CH₂ --. Fora description of the use of sodium borohydride for the selectivereduction of aldehydes, see S. Chaikin and W. Brown, J. Am. Chem. Soc.,71, 122 (1949).

The aldehydes of Formula XVIII can be prepared by the procedure shown inEquation 15 starting with the appropriate nitriles of Formula XIX (shownfor the specific example of J=J₁₆).

EQUATION 15 ##STR25## wherein R₁, R₃, R₄ and Q₁ are as previouslydefined.

Although the reaction of Equation 15 is shown specifically for J=J₁₆,this transformation is equally applicable to all of the ring systems(L=--CH₂ --) except J₅, J₆, J₁₀, and J₁₁. The reaction shown in Equation15 can be carried out according to the procedures of H. C. Brown, C. J.Shoaf, and C. P. Garg, Tetrahedron Lett., 9 (1959), and J. A. Marshall,N. H. Andersen, and J. W. Schlicher, J. Org. Chem., 35, 858 (1970).

Benzoic acid derivatives of Formula XVII (shown below in Equation 16 forthe specific example of J=J₁₆) can be prepared by hydrolysis of theappropriate nitriles of Formula XIX which are, in turn, prepared by aSandmeyer reaction on the corresponding aniline derivatives XX.

EQUATION 16 ##STR26## wherein R₁, R₃, R₄ and Q₁ are as previouslydefined.

As before, while the reactions of Equation 16 are shown specifically forJ=J₁₆, these steps are applicable to all ring systems where J is otherthan J₅, J₆, J₁₀ or J₁₁, and L is --CH₂ --.

EQUATION 16(a)

The diazotization and cuprous cyanide coupling reaction of Equation16(a) is best carried out according to the procedure described inOrganic Syntheses, Coll. Vol. I, p. 514.

EQUATION 16(b)

Nitriles of Formula XIX are most easily hydrolyzed to the desiredcarboxylic acids XVII by heating at reflux temperature in concentratedsolutions of sulfuric acid or by treatment with 100% phosphoric acid andsubsequent exposure to nitrous acid. The products are typically isolatedby extraction into aqueous base solution followed by washing with asuitable organic solvent such as ether and acidification of the waterlayer. For a compilation of references dealing with this process, see R.Wagner and H. Zook, "Synthetic Organic Chemistry," John Wiley & Sons,Inc., New York, 1953, p. 412.

A method similar to that described in Equation 16 above can be appliedto the synthesis of phenols of Formula VIII as shown below in Equation17 (shown for the specific example of J=J₁₆).

EQUATION 17 ##STR27## wherein R₁, R₃, R₄ and Q₁ are as previouslydefined.

The reaction of Equation 17 is applicable to ring systems J₁, J₂, J₃,J₄, J₅, J₆, J₇, J₈, J₉, J₁₀, J₁₁, J₁₂, J₁₃, J₁₄, J₁₆, J₁₈, J₂₀ and J₂₁where L is 0. The diazotization and hydrolysis reactions shown inEquation 17 can be carried out according to the following procedures:Stevens and Beutel, J. Am. Chem. Soc., 63, 311 (1941); Grillot andGormley, J. Am. Chem. Soc., 67, 1968 (1945); and Mosettig and Stuart, J.Am. Chem. Soc., 61, 1 (1939).

The requisite aniline derivatives of Formula XX can be prepared in astraightforward manner by reduction of the corresponding nitro compoundsof Formula XXI as shown in Equation 18 (for the example where J=J₁₆).

EQUATION 18 ##STR28## wherein R₁, R₃, R₄, and Q are as previouslydefined.

Although the reaction of Equation 18 is shown specifically for J=J₁₆,this reduction is applicable to all ring systems J₁ -J₂₁. There exists awide variety of methods for effecting the reduction of aromatic nitrogroups to the corresponding aniline derivatives. One of the more commonprocedures involves treating the nitro compounds of Formula XXI with aslight excess of stannous chloride dihydrate in concentratedhydrochloric acid solution at temperatures between 25° and 80° C.Alternatively, reduction may be accomplished with iron powder in glacialacetic acid solution as described by Hazlet and Dornfeld, J. Am. Chem.Soc., 66, 1781 (1944), and by West in J. Chem. Soc., 127, 494 (1925).For a general review, see Groggins, "Unit Processes In OrganicSynthesis," McGraw-Hill Book Co., New York, 1947, pp. 73-128.

Many of the substituted aromatic nitro compounds of Formula XXI (whereit is understood that all ring systems defined in the Summary ofInvention are represented) can be synthesized by methods taught in U.S.patent application Ser. No. 499,443, filed on May 31, 1983, or by any ofseveral possible synthetic routes known to one skilled in the art.

The intermediate functionalized toluene derivatives of Formula XV(L=--CH₂ --) may also be prepared by straightforward synthetic routesknown to one skilled in the art.

The synthesis of heterocyclic amines such as these depicted in FormulaIII has been reviewed in "The Chemistry of Heterocyclic Compounds," aseries published by Interscience Publ., New York and London.Aminopyrimidines are described by D. J. Brown in "The Pyrimidines," Vol.XVI of the series mentioned above. The 2-amino-1,3,5-triazines can beprepared according to the method described by E. M. Smolin and L.Rapaport in "s-Triazines and Derivatives," Vol. XIII.

Agriculturally suitable salts of compounds of Formula I are also usefulherbicides and can be prepared in a number of ways known to the art. Forexample, metal salts can be made by treating compounds of Formula I witha solution of an alkali or alkaline earth metal salt having asufficiently basic anion (e.g., hydroxide, alkoxide, carbonate orhydride). Quaternary amine salts can be made by similar techniques.Detailed examples of such techniques are given in U.S. Pat. No.4,127,405.

The compounds of this invention and their preparation are furtherillustrated by the following examples wherein temperatures are given indegrees centigrade and all parts are by weight unless otherwisedesignated.

EXAMPLE 1 2,6-Dimethylbenzoic acid, methyl ester

A solution of 10 g of 2,6-dimethylbenzoic acid in 22 g thionyl chloridewas stirred at reflux temperature for 2 hours. Removal of the excessthionyl chloride afforded the crude acid chloride as a yellow oil. Thisintermediate was added to a stirred solution of 4 mL of methanol in 10.8mL pyridine at 65°-70° C. After completion of the addition, theresulting mixture was stirred at room temperature for 2 hours and thenpoured into 75 mL ice-water. The aqueous layer was extracted with four50-mL portions of ether and the combined organic extracts werebackwashed with saturated sodium bicarbonate solution, 5% aqueoushydrochloric acid, and water. Drying and evaporation of the solvent gavea pale yellow oil which was purified by bulb-to-bulb distillation(40°-50° C., 0.5 mm Hg) to afford 9.5 g of pure 2,6-dimethylbenzoicacid, methyl ester as a colorless liquid; IR (film) 1725 cm⁻¹ ;NMR(CDCl₃) δ 2.3 (s, 6H), 3.9 (s, 3H), 7.0-7.4 (m, 3H).

EXAMPLE 2 2,6-Bis(α,α'-bromomethyl)benzoic acid, methyl ester

A mixture of 5.0 g of the product from Example 1, 11.1 g ofN-bromosuccinimide and 0.1 g of azoisobutyronitrile in 76 mL carbontetrachloride was heated at reflux temperature for one hour. Thesolution was cooled to room temperature, filtered, and the filtrateconcentrated in vacuo to give a light orange oil. Treatment withether-hexane (1:1, v/v) afforded 3.0 g of pure2,6-bis(α,α'-bromomethyl)benzoic acid, methyl ester as a white solid,m.p. 67°-70° C.; IR(nujol) 1720 cm⁻¹ ; NMR(CDCl₃) δ 4.0 (s, 3H), 4.65(s, 4H), 7.5 (s, 3H).

EXAMPLE 3 7-Bromomethylphthalide

The product from Example 2 (2.0 g) was added to 8 mL of concentratedsulfuric acid and the suspension was warmed to about 60° C. for 3 hours.The solution was allowed to cool and was poured into ice-water. Theresulting white precipitate was collected by filtration, washed wellwith water and dried. Recrystallization from acetone gave 1.0 g of pure7-bromomethylphthalide as a white powder, m.p. 127.5°-131° C.; IR(KBr)1755 cm⁻¹ ; NMR(CDCl₃) δ5.0 (s, 2H), 5.29 (s, 2H), 7.4 (br d, 1H), 7.5(br d, 1H), 7.6 (dd, 1H).

EXAMPLE 4 7-[[(Amino)(imino)methyl]thiomethyl]phthalide

A solution of 1.0 g of the product from Example 3 in 10 mLtetrahydrofuran was treated with 0.33 g of thiourea and the suspensionwas warmed to reflux temperature for 15 minutes as a thick, whiteprecipitate formed. The reaction mixture was allowed to cool and wasfiltered. The collected solid was washed with 1-chlorobutane and dried.The yield of the pure title compound was 1.2 g as a white powder, m.p.206°-211° C. (dec.); NMR(DMSO-d₆) δ 4.8 (s, 2H), 5.4 (s, 2H), 7.61 (brt, 2H), 7.73 (br t, 1H), 9.1 (brs, 1H), 9.23 (br s, 2H).

EXAMPLE 5 1,3-Dihydro-1-oxo-benzo[c]furan-7-methanesulfonyl chloride

A solution of 9.4 g of the product from Example 4 in 77 mL of 50%aqueous acetic acid was cooled to 0° C. and treated with 8 mL of liquidchlorine. Following the addition, the mixture was stirred at 0°-10° C.for 2 hours, filtered, and the solid was washed well with water. Theyield of 1,3-dihydro-1-oxo-benzo[c]furan-7-methanesulfonyl chloride was5.6 g as an off-white solid, m.p. 103°-105.5° C. (dec); IR(KBr) 1740,1355, 1200 cm⁻¹.

EXAMPLE 6 1,3-Dihydro-1-oxo-benzo[c]furan-7-methanesulfonamide

A solution of 5.6 g of the product from Example 5 in 50 mLtetrahydrofuran was cooled to 0° C. under an atmosphere of nitrogen andwas treated with 1.5 mL of anhydrous ammonia. The resulting suspensionwas stirred at room temperature for 3 hours. The insoluble solids werecollected by filtration and were washed with water and dried. The yieldof the title compound was 3.8 g as a white powder, m.p. b 192°-195° C.;IR(KBr) 3340, 3240, 1740, 1130 cm⁻¹ ; NMR(DMSO-d₆ /CDCl₃) δ 4.9 (s, 2H),5.4 (s, 2H), 6.7 (br s, 2H), 7.5-7.8 (m, 3H).

EXAMPLE 7 1,3-Dihydro-1-oxo-benzo[c]furan-7-methanesulfonyl isocyanate

A solution of 2.0 g of the product from Example 6 in 25 mL thionylchloride was heated at reflux temperature for 18 hours. The reactionsolution was allowed to cool to room temperature and excess thionylchloride was removed in vacuo. The resulting residue was treated with 16g of 10% phosgene in toluene and 5 drops of pyridine. This mixture wasstirred at reflux temperature for 3 hours. The solution was allowed tocool, filtered under a stream of nitrogen, and the filtrate wasconcentrated to give 1,3-dihydro-1-oxo-benzo[c]furan-7-methanesulfonylisocyanate as an orange oil. The infrared spectrum of this compounddisplayed a characteristic isocyanate stretching absorption at 2240 cm⁻¹as well as a carbonyl stretching signal at 1750 cm⁻¹.

EXAMPLE 81,3-Dihydro-N-[(4,6-dimethoxypyrimidine-2-yl)aminocarbonyl]-1-oxo-benzo[c]furan-7-methanesulfonamide

A solution of 8 mmole of the product from Example 7 in 16 mL dryacetonitrile was treated with 1.2 g of 2-amino-4,6-dimethoxypyrimidineand the mixture was heated to 45°-50° C. under an atmosphere of nitrogenfor 2 hours. After being stirred at room temperature for an additional12 hours, the suspension was filtered and the collected solid was washedwell with warm acetonitrile. The yield of the title compound was 1.0 gas a yellow powder, m.p. 181°-184° C. (dec.); IR(KBr) 1765, 1710, 1620,1355 cm⁻¹ ; NMR(CDCl₃) δ 3.83 (s, 6H), 5.27 (s, 2H), 5.41 (s, 2H), 5.76(s, 1H), 7.35 (br s, 1H), 7.5 (m, 1H), 7.7 (m, 2H), 12.4 (br s, 1H).##STR29##

By applying the procedures of Examples 1 through 8, the compounds shownin Tables 1 and 2, following, can be prepared.

                                      TABLE 1                                     __________________________________________________________________________    General Formula 1                                                                                                     m.p.                                  J n L  R.sub.1                                                                           R.sub.9       X     Y        (°C.)                          __________________________________________________________________________    J.sub.1                                                                         0 CH.sub.2                                                                         H   CH.sub.3      CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   CH.sub.3      OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   CH.sub.3      CH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                         0 CH.sub.2                                                                         H   CH.sub.3      OCH.sub.3                                                                           C.sub.2 H.sub.5                                J.sub.1                                                                         0 CH.sub.2                                                                         H   CH.sub.3      CH.sub.3                                                                            OC.sub.2 H.sub.5                               J.sub.1                                                                         0 CH.sub.2                                                                         H   CH.sub.3      OCH.sub.3                                                                           CH.sub.2 OCH.sub.3                             J.sub.1                                                                         0 CH.sub.2                                                                         H   CH.sub.3      Cl    OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   CH.sub.3      Br    OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   CH.sub.3      OCH.sub.3                                                                           CH.sub.2 F                                     J.sub.1                                                                         0 CH.sub.2                                                                         H   CH.sub.3      OCH.sub.3                                                                           CF.sub.3                                       J.sub.1                                                                         1 CH.sub.2                                                                         H   CH.sub.3      OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   C.sub.2 H.sub.5                                                                             OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub. 2                                                                        H   n-C.sub.3 H.sub.7                                                                           OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   CH(CH.sub.3).sub.2                                                                          OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   H             CH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                         0 CH.sub.2                                                                         H   H             OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   H             CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   H             OCH.sub.3                                                                           Cl                                             J.sub.1                                                                         0 O  H   H             CH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                         0 O  H   H             CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 O  H   H             OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 O  H   H             OCH.sub.3                                                                           Cl                                             J.sub.1                                                                         0 O  H   CH.sub.3      OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 O  H   CH.sub.3      CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 O  H   CH.sub.3      CH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                         0 O  H   CH.sub.3      Cl    OCH.sub.3                                      J.sub.1                                                                         0 O  H   CH.sub.3      Br    OCH.sub.3                                      J.sub.1                                                                         0 O  H   C.sub.2 H.sub.5                                                                             OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 O  H   n-C.sub.3 H.sub.7                                                                           OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 O  H   CH(CH.sub.3).sub.2                                                                          OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         1 O  H   CH.sub.3      OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         5-F CH.sub.3      OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         6-Cl                                                                              CH.sub.3      OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         6-Br                                                                              CH.sub.3      OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         6-CH.sub.3                                                                        CH.sub.3      OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         6-OCH.sub.3                                                                       CH.sub.3      OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 O  H   CH.sub.3      OCH.sub.2 CF.sub.3                                                                  CH.sub.3                                       J.sub.1                                                                         0 O  H   CH.sub.3      OCHF.sub.2                                                                          OCH.sub.3                                      J.sub.1                                                                         0 O  H   CH.sub.3      OCH.sub.3                                                                           CH(CH.sub.3).sub.2                             J.sub.1                                                                         0 O  H   CH.sub.3      OCH.sub.3                                                                           cyclopropyl                                    J.sub.1                                                                         0 O  H   CH.sub.3      OCH.sub.3                                                                           C.tbd.CH                                       J.sub.1                                                                         0 O  H   CH.sub.3      OCH.sub.3                                                                           NH.sub.2                                       J.sub.1                                                                         0 O  H   CH.sub.3      OCH.sub.3                                                                           NH.sub.2                                       J.sub.1                                                                         0 O  H   CH.sub.3      OCH.sub.3                                                                           N(CH.sub.3).sub.2                              J.sub.1                                                                         0 O  H   CH.sub.3      OCH.sub.3                                                                           OCH.sub.2 CH.sub.2 F                           J.sub.1                                                                         0 O  H   CH.sub.3      OCH.sub.3                                                                           SCH.sub.3                                      J.sub.1                                                                         0 O  H   CH.sub.3      OCH.sub.3                                                                           OCH.sub.2 CH═CH.sub.2                      J.sub.1                                                                         0 O  H   CH.sub.3      OCH.sub.3                                                                           OCH.sub.2 CH.sub.2 OCH.sub.3                   J.sub.1                                                                         0 O  H   CH.sub.3      OCH.sub.3                                                                           OCH.sub.2 C.tbd.CH                             J.sub.1                                                                         0 O  H   CH.sub.3      OCH.sub.3                                                                           CH(OCH.sub.3).sub.2                            J.sub.1                                                                         0 O  H   CH.sub.3      OCH.sub.3                                                                           C(CH.sub.3)(OCH.sub.3).sub.2                   J.sub.1                                                                         0 O  H   CH.sub.3      OCH.sub.3                                                                           1,3-dioxolan-                                                                 2-yl                                           J.sub.1                                                                         0 O  H   CH.sub.3      OCH.sub.3                                                                           2-methyl-1,3--                                                                diololan-2-yl                                  J.sub.1                                                                         0 O  H   CH.sub.3      OCH.sub.3                                                                           CH(OC.sub.2 H.sub.5).sub.2                     J.sub.1                                                                         0 O  H   CH.sub.3      OCH.sub.3                                                                           C(CH.sub.3)(OC.sub.2 H.sub.5).sub.2            J.sub.1                                                                         0 O  H   CH.sub.3      OCH.sub.3                                                                           NHCH.sub.3                                     J.sub.1                                                                         0 O  H   CH.sub.3      Cl    NHCH.sub.3                                     J.sub.1                                                                         0 O  H   --CH.sub.2 CN OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 O  H   --(CH.sub.2).sub.3 CN                                                                       CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   OH            CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   --(CH.sub.2).sub.3 CH(CH.sub.3).sub. 2                                                      Cl    OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   --CF.sub.2 H  OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   --CH.sub.2 CH.sub.2 Cl                                                                      Cl    OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   --(CH.sub.2).sub.5 Cl                                                                       CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   --CH.sub.2 OCH.sub.3                                                                        Cl    OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   --(CH.sub.2).sub.4 OCH.sub.3                                                                CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   --CH.sub.2 CH═CH.sub.2                                                                  OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   --CH.sub.2 CH═CHCH.sub.3                                                                CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   --CH.sub.2 C.tbd.CH                                                                         OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   --CH.sub.2 C.tbd.C--CH.sub.3                                                                Cl    OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   --(CH.sub.2).sub.4 C.tbd.CH                                                                 CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   --OCH.sub.3   CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   --O(CH.sub.2).sub.4 CH.sub.3                                                                Cl    OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   --C.sub.6 H.sub. 5                                                                          CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   cyclopropyl   OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   cyclohexyl    OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   cyclopropylmethyl                                                                           OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   cyclohexylmethyl                                                                            Cl    OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   --C(O)CH.sub.3                                                                              OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   --C(O)(CH.sub.2).sub.5 H                                                                    Cl    OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   --CO.sub.2 C.sub.2 H.sub.5                                                                  Br    OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   --CO.sub.2 (CH.sub.2).sub.4 H                                                               Cl    OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   --CH.sub.2 C.sub.6 H.sub.5                                                                  OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   --CH.sub.2 --CH═CH--CH.sub.2 Cl                                                         CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   --CH.sub.2 C.tbd.C--CH.sub.2 Cl                                                             Cl    OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   --CH.sub.2 C(O)CH.sub.3                                                                     OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   --CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                      OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub. 2                                                                        H   H             CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   H             CH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                         0 CH.sub.2                                                                         H   H             Cl    OCH.sub.3                                      J.sub.1                                                                         0 O  H   H             OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 O  H   H             CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 O  H   H             CH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                         0 O  H   H             Cl    OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   n-C.sub.4 H.sub.9                                                                           CH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                         0 CH.sub.2                                                                         H   n-C.sub.4 H.sub.9                                                                           CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   n-C.sub.4 H.sub.9                                                                           OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H   n-C.sub.4 H.sub.9                                                                           Cl    OCH.sub.3                                      J.sub.1                                                                         0 O  H   n-C.sub.4 H.sub.9                                                                           CH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                         0 O  H   n-C.sub.4 H.sub.9                                                                           CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 O  H   n-C.sub.4 H.sub.9                                                                           OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 O  H   n-C.sub.4 H.sub.9                                                                           Cl    OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   CH.sub.3      OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   CH.sub.3      OCH.sub.3                                                                           CH.sub.3                                       J.sub. 7                                                                        --                                                                              CH.sub.2                                                                         H   CH.sub.3      CH.sub.3                                                                            CH.sub.3                                       J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   CH.sub.3      Cl    OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   CH.sub.3      Br    OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   CH.sub.3      OCH.sub.3                                                                           C.sub.3 H.sub.5                                J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   CH.sub.3      CH.sub.3                                                                            OC.sub.2 H.sub.5                               J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   CH.sub.3      OCH.sub.3                                                                           CH.sub.2 OCH.sub.3                             J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   CH.sub.3      OCH.sub.3                                                                           CH.sub.2 F                                     J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   CH.sub.3      OCH.sub.3                                                                           CF.sub.3                                       J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   H             OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   C.sub.2 H.sub.5                                                                             OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   n-C.sub.3 H.sub.7                                                                           OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   CH(CH.sub.3).sub.2                                                                          OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              O  H   CH.sub.3      OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         7-Cl                                                                              CH.sub.3      OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              O  7-Br                                                                              CH.sub.3      OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         6-F CH.sub.3      OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              O  7-CH.sub.3                                                                        CH.sub.3      OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              O  7-OCH.sub.3                                                                       CH.sub.3      OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   CH.sub.3      OCH.sub.2 CF.sub.3                                                                  OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   CH.sub.3      OCHF.sub.2                                                                          OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   CH.sub.3      OCH.sub.3                                                                           cyclopropyl                                    J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   CH.sub.3      OCH.sub.3                                                                           NHCH.sub.3                                     J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   CH.sub.3      OCH.sub.3                                                                           N(CH.sub.3).sub.2                              J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   CH.sub.3      OCH.sub.3                                                                           OCH.sub.2 CH═CH.sub.2                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   CH.sub.3      OCH.sub.3                                                                           CH(OCH.sub.3).sub.2                            J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   CH.sub.3      OCH.sub.3                                                                           1,3-dioxola-                                                                  2-yl                                           J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   CH.sub.3      OCH.sub.3                                                                           CH(OC.sub.2 H.sub.5).sub.2                     J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   CH.sub.3      Cl    NHCH.sub.3                                     J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   CH.sub.3      OCH.sub.3                                                                           -- C.tbd.CH                                    J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   CH.sub.3      OCH.sub.3                                                                           C(CH.sub.3)(OCH.sub.3).sub.2                   J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   OH            OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   (CH.sub.2).sub.2 CH(CH.sub.3).sub.2                                                         Cl    OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   CH.sub.2 CH.sub.2 Cl                                                                        OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   (CH.sub.2).sub.5 Cl                                                                         CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   CH.sub.2 OCH.sub.3                                                                          Cl    OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   (CH.sub.2).sub.2 OCH.sub.3                                                                  Cl    OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   CH.sub.2 CH═CH.sub.2                                                                    OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   CH.sub.2 CH═CHCH.sub.2 Cl                                                               CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   CH.sub.2 CH═CHCH.sub.3                                                                  CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   CH.sub.2 C.tbd.CCH.sub.3                                                                    OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   OCH.sub.3     Cl    OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   O(CH.sub.2).sub.4 CH.sub. 3                                                                 Cl    OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   C.sub.6 H.sub.5                                                                             OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   cyclopropyl   Cl    OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   cyclopropyl   OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   C(O)CH.sub.3  OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   CO.sub.2 CH.sub.3                                                                           OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   CH.sub.2 C.sub.6 H.sub.5                                                                    Cl    OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   CH.sub.2 CH═CHCl                                                                        Cl    OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H   CH(CH.sub.3)CO.sub.2 CH.sub.3                                                               Cl    OCH.sub.3                                      __________________________________________________________________________

    TABLE 1a      General Formula 1a                 m.p. J n L Q Q.sub.1 Q.sub.2 R.sub.1     R.sub.2 R.sub.3 R.sub.4 R.sub.5 R.sub.6 R.sub.7 R.sub.8 X Y (°C.)       J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3     OCH.sub.3  J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- --     OCH.sub.3 CH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- --     -- Cl OCH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- --     Br OCH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- --     OCH.sub.3 C.sub.2 H.sub.5 J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- --     -- -- -- -- CH.sub.3 OC.sub.2 H.sub.5 J.sub.2 0 CH.sub.2 -- -- -- H     CH.sub.3 -- -- -- -- -- -- OCH.sub.3 CH.sub.2 OCH.sub.3 J.sub.2 0     CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 CH.sub.2 F     J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3     CF.sub.3 J.sub.2 0 CH.sub.2 -- -- -- H H -- -- -- -- -- -- OCH.sub.3     OCH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- H C.sub.2 H.sub.5 -- -- -- -- --     -- OCH.sub.3 OCH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- H n-C.sub.3 H.sub.7     -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- H     CH(CH.sub.3).sub.2 -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.2 1     CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.2 0 O -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.2 0 O -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 CH.sub.3     J.sub.2 0 O -- -- -- H CH.sub.3 -- -- -- -- -- -- Cl OCH.sub.3 J.sub.2 0     O -- -- -- H CH.sub.3 -- -- -- -- -- -- Br OCH.sub.3 J.sub.2 1 O -- --     -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.2 0 O -- -- --     H C.sub.2 H.sub.5 -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.2 0     CH.sub.2 -- -- -- 6-Br CH.sub.3 -- -- -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.2 0 CH.sub.2 -- -- -- 6-Cl CH.sub.3 -- -- -- -- -- -- OCH.sub.3     OCH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- 5-F CH.sub.3 -- -- -- -- -- --     OCH.sub.3 OCH.sub.3 J.sub.2 0 O -- -- -- 6-CH.sub.3 CH.sub.3 -- -- -- --     -- -- OCH.sub.3 OCH.sub.3 J.sub.2 0 O -- -- -- 6-OCH.sub.3 CH.sub.3 --     -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.3 0 CH.sub.2 -- -- -- H -- H H     -- -- -- -- OCH.sub.3 OCH.sub.3 181-184,d J.sub.3 0 CH.sub.2 -- -- -- H     -- H H -- -- -- -- CH.sub.3 OCH.sub.3 180-185,d J.sub.3 0 CH.sub.2 -- --     -- H -- H H -- -- -- -- CH.sub.3 CH.sub.3 J.sub.3 0 CH.sub.2 -- -- -- H     -- H H -- -- -- -- Cl OCH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3     -- -- -- -- -- -- OCH.sub.3 CH(CH.sub.3).sub.2 J.sub.2 0 CH.sub.2 -- --     -- H CH.sub.3 --  -- -- -- -- -- Cl NHCH.sub.3 J.sub.2 0 CH.sub.2 -- --     -- H CH.sub.3 -- -- -- -- -- -- Cl OCF.sub.2 H J.sub.2 0 CH.sub.2 -- --     -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.2 CF.sub.3 OCH.sub.3 J.sub.2 0     CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCF.sub.2 H OCF.sub.2 H     J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3     cyclopropyl J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- --     OCH.sub.3 NHCH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- --     -- -- OCH.sub.3 N(CH.sub.3).sub.2 J.sub. 2 0 CH.sub.2 -- -- -- H     CH.sub.3 -- -- -- -- -- --OCH.sub.3 OCH.sub.2 CH═CH.sub.2 J.sub.2 0     CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 CH(OCH.sub.3).su     b.2 J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3     1,3-dioxola-                2-yl J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3     -- -- -- -- -- -- OCH.sub.3 CH(OC.sub.2 H.sub.5).sub.2 J.sub.2 0     CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 C.tbd.CH     J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3     OCH.sub. 2 CH.sub.2 OCH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 --     -- -- -- -- -- OCH.sub.3 SCH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- H     CH.sub.3 -- -- -- -- -- -- OCF.sub.2 H OCH.sub.3 J.sub.2 0 CH.sub.2 --     -- -- H CH.sub.3 -- -- -- -- -- -- CH.sub.3 1,3-dioxolan-     2-yl J.sub.3 0 CH.sub.2 -- -- -- H -- H H -- -- -- -- CH.sub.3 OCH.sub.2     C.tbd.CH J.sub.3 0 CH.sub.2 -- -- -- H -- H H -- -- -- -- Br OCH.sub.3     J.sub.3 0 CH.sub.2 -- -- -- H -- H H -- -- -- -- OCH.sub.3 C.sub.2     H.sub.5 J.sub.3 0 CH.sub.2 -- -- -- H -- H H -- -- -- -- CH.sub.3     OC.sub.2 H.sub.5 J.sub.3 0 CH.sub.2 -- -- -- H -- H H -- -- -- --     CH.sub.3 CH.sub.2 OCH.sub.3 J.sub.3 0 CH.sub.2 -- -- -- H -- H H -- --     -- -- OCH.sub.3 CH.sub.2 F J.sub.3 0 CH.sub.2 -- -- -- H -- H H -- -- --     -- OCH.sub.3 CF.sub.3 J.sub.3 1 CH.sub.2 -- -- -- H -- H H -- -- -- --     OCH.sub.3 OCH.sub.3 J.sub.3 1 CH.sub.2 -- -- -- H -- CH.sub.3 H -- -- --     -- OCH.sub.3 OCH.sub.3 J.sub.3 0 O -- -- -- H -- H H -- -- -- --     OCH.sub.3 CH.sub.3 J.sub. 3 1 CH.sub.2 -- -- -- H -- CH.sub.3 H -- -- --     -- CH.sub.3 CH.sub.3 J.sub.3 1 CH.sub.2 -- -- -- H -- CH.sub.3 H -- --     -- -- CH.sub.3 OCH.sub.3 J.sub.3 1 CH.sub.2 -- -- -- H -- CH.sub.3 H --     -- -- -- OCH.sub.3 OCH.sub.3 J.sub.3 1 CH.sub.2 -- -- -- H -- CH.sub.3 H     -- -- -- -- Cl OCH.sub.3 J.sub.3 1 O -- -- -- H -- CH.sub.3 H -- -- --     -- CH.sub.3 CH.sub.3 J.sub.3 1 O -- -- -- H -- CH.sub.3 H -- -- -- --     OCH.sub.3 CH.sub.3 J.sub.3 1 O -- -- -- H -- CH.sub.3 H -- -- -- -- Cl     OCH.sub.3 J.sub.3 0 CH.sub.2 -- -- -- H -- CH.sub.3 H -- -- -- --     OCH.sub.3 OCH.sub.3 J.sub.3 0 O -- -- -- H -- H H -- -- -- -- OCH.sub.3     OCH.sub.3 J.sub.3 0 O -- -- -- H -- H H -- -- -- -- OCH.sub.3 CH.sub.3     J.sub.3 0 O -- -- -- H -- H H -- -- -- -- Cl OCH.sub.3 J.sub.3 0 O -- --     -- H -- H H -- -- -- -- Br OCH.sub.3 J.sub.3 0 O -- -- -- H -- H H -- --     -- -- CH.sub.3 CH.sub.3 J.sub.3 0 CH.sub.3 -- -- -- H -- H H -- -- -- --     CH.sub.3 CH.sub.3 J.sub.3 0 CH.sub.2 -- -- -- H --  H H -- -- -- --     OCH.sub.3 CH.sub.3 J.sub.3 0 CH.sub.2 -- -- -- H -- H H -- -- -- --     OCH.sub.3 OCH.sub.3 J.sub.3 0 CH.sub.2 -- -- -- H -- H H -- -- -- -- Cl     OCH.sub.3 J.sub.3 0 CH.sub.2 -- -- -- 5-F -- H H -- -- -- -- OCH.sub.3     OCH.sub.3 J.sub.3 0 CH.sub.2 -- -- -- 6-Cl -- H H -- -- -- -- OCH.sub.3     OCH.sub.3 J.sub.3 0 CH.sub.2 -- -- -- 6-Br -- H H -- -- -- -- OCH.sub.3     OCH.sub.3 J.sub.3 0 O -- -- -- 5-CH.sub.3 -- H H -- -- -- -- OCH.sub.3     OCH.sub.3 J.sub.3 0 O -- -- -- 6-OCH.sub.3 -- H H -- -- -- -- OCH.sub.3     OCH.sub.3 J.sub.3 1 O -- -- -- H -- H H -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.4 0 CH.sub.2 -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.4 1 CH.sub.2 -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.4 0 O -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.4     1 O -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.4 0     CH.sub.2 -- -- -- H -- -- -- -- -- -- -- Cl OCH.sub.3 J.sub.4 0 O -- --     -- H -- -- --  -- -- -- -- Cl OCH.sub.3 J.sub.5 0 -- -- -- -- H CH.sub.3     -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.5 0 -- -- -- -- H CH.sub.3     -- -- -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.5 0 -- -- -- -- H CH.sub.3 --     -- -- -- -- -- CH.sub.3 CH.sub.3 J.sub.5 0 -- -- -- -- H CH.sub.3 -- --     -- -- -- -- Cl OCH.sub.3 J.sub.5 1 -- -- -- -- H CH.sub.3 -- -- -- -- --     -- OCH.sub.3 OCH.sub.3 J.sub.5 0 -- -- -- -- H H -- -- -- -- -- --     OCH.sub.3 OCH.sub.3 J.sub.6 0 -- -- -- --  H CH.sub.3 -- -- -- -- -- --     OCH.sub.3 OCH.sub.3 J.sub.6 0 -- -- -- -- H CH.sub.3 -- -- -- -- -- --     Cl OCH.sub.3 J.sub.6 0 -- -- -- -- H CH.sub.3 -- -- -- -- -- -- CH.sub.3     OCH.sub.3 J.sub.6 0 -- -- -- -- H H -- -- -- -- -- -- OCH.sub.3 OCH.sub.3      J.sub.6 1 -- -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.8 -- CH.sub.2 -- -- -- H -- H -- -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.8 -- CH.sub.2 -- -- -- H -- H -- -- -- -- -- OCH.sub.3 CH.sub.3     J.sub.8 -- CH.sub.2 -- -- -- H -- H -- -- -- -- -- Cl OCH.sub.3 J.sub.8     -- CH.sub.2 -- -- -- H -- H -- -- -- -- -- Br OCH.sub.3 j.sub.8 --     CH.sub.3 -- -- -- H -- H -- -- -- -- -- OCH.sub.3 C.sub.2 H.sub.5     J.sub.8 -- CH.sub.2 -- -- -- H -- H -- -- -- -- -- CH.sub.3 OC.sub.2     H.sub.5 J.sub.8 -- CH.sub.2 -- -- -- H -- H -- -- -- -- -- OCH.sub.3     CH.sub.2 OCH.sub.3 J.sub.8 -- CH.sub.2 -- -- -- H -- H -- -- -- -- --     OCH.sub.3 CH.sub.2 F J.sub.8 -- CH.sub.2 -- -- -- H -- H --  -- -- -- --     OCH.sub.3 CF.sub.3 J.sub.8 -- O -- -- -- H -- H -- -- -- -- -- OCH.sub.3     OCH.sub.3 J.sub.8 -- O -- -- -- H -- H -- -- -- -- -- Cl OCH.sub.3     J.sub.8 -- CH.sub.2 -- -- -- 7-Cl -- H -- -- -- -- -- OCH.sub.3 OCH.sub.3      J.sub.9 -- CH.sub.2 -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.9 -- CH.sub.2 -- -- -- H -- -- -- -- -- -- -- Cl OCH.sub.3 J.sub.9     -- O -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.10 -- --     -- --  -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.10 --     -- -- -- -- H CH.sub.3 -- -- -- -- -- -- Cl OCH.sub.3 J.sub.10 -- -- --     -- -- H C.sub.2 H.sub.5 -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.11     -- -- -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.11     -- -- -- -- -- H C.sub.2 H.sub.5 -- -- -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.12 -- CH.sub.2 -- -- -- H -- H -- -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.12 -- CH.sub.2 -- -- -- H -- H -- -- --  -- -- OCH.sub.3 CH.sub.3     J.sub.12 -- CH.sub.2 -- -- -- H --H -- -- -- -- -- Cl OCH.sub.3 J.sub.12     -- CH.sub.2 -- -- -- H -- H -- -- -- -- -- Br OCH.sub.3 J.sub.12 --     CH.sub.2 -- -- -- H -- CH.sub.3 -- -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.12 -- O -- -- -- H -- H -- -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.12 -- O -- -- -- H -- H -- -- -- -- -- Cl OCH.sub.3 J.sub.12 -- O     -- -- -- H -- CH.sub.3 -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.13 --     CH.sub.2 O -- -- H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.13 --     CH.sub.2 O -- -- H -- -- -- -- -- -- -- Cl OCH.sub.3 J.sub.13 -- O O --     -- H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.13 -- O O -- -- H --     -- -- -- -- -- -- Cl OCH.sub.3 J.sub.13 -- CH.sub.2 CH.sub.2 -- -- H --     -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.13 -- CH.sub.2 CH.sub.2 --     -- H -- -- -- -- -- -- -- Cl OCH.sub.3 J.sub.13 -- O CH.sub.2 -- -- H --     -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.13 -- O CH.sub.2 -- -- H --     -- -- -- -- -- -- Cl OCH.sub.3 J.sub.14 -- CH.sub.2 -- -- -- H -- -- --     -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.14 -- CH.sub.2 -- -- -- H -- -- --     -- -- -- -- Cl OCH.sub.3 J.sub.14 -- O -- -- -- H -- -- -- -- -- -- --     OCH.sub.3 OCH.sub.3 J.sub.14 -- O -- -- -- H -- -- -- -- -- -- -- Cl     OCH.sub.3 J.sub.15 -- -- -- O -- H -- CH.sub.3 H H -- -- -- OCH.sub.3     OCH.sub.3 J.sub.15 -- -- -- O -- H -- CH.sub.3 H H -- -- -- OCH.sub.3     CH.sub.3 J.sub.15 -- -- -- O -- H -- H H CH.sub.3 -- -- -- CH.sub.3     CH.sub.3 J.sub.15 -- -- -- O -- H -- H H CH.sub.3 -- -- -- Cl OCH.sub.3     J.sub.15 -- -- -- O -- H -- CH.sub.3 H H -- -- -- Br OCH.sub.3 J.sub.15     -- -- -- O -- H -- H H CH.sub.3 -- -- -- OCH.sub.3 C.sub.2 H.sub.5     J.sub.15 -- -- -- O -- H -- CH.sub.3 H H -- -- -- CH.sub.3 OC.sub.2     H.sub.5 J.sub.15 -- -- -- O -- H -- CH.sub.3 H H -- -- -- OCH.sub.3     CH.sub.2 OCH.sub.3 J.sub.15 -- -- -- O -- H -- H H C.sub.2 H.sub.5 -- --     -- OCH.sub.3 CF.sub.3 J.sub.15 -- -- -- O -- H -- CH.sub.3 CH.sub.3 H --     -- -- OCH.sub.3 OCH.sub.3 J.sub.15 -- -- -- O -- H -- CH.sub.3 H     CH.sub.3 -- -- -- OCH.sub.3 OCH.sub.3 J.sub.15 -- -- -- O -- H --     CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3 CH.sub.3 J.sub.15 -- -- -- O -- H     -- CH.sub.3 H CH.sub.3 -- -- -- CH.sub.3 CH.sub.3 J.sub.15 -- -- -- O --     H -- CH.sub.3 H CH.sub.3 -- -- -- Cl OCH.sub.3 J.sub.15 -- -- -- O -- H     -- CH.sub.3 H CH.sub.3 -- -- -- Br OCH.sub.3 J.sub.15 -- -- -- O -- H --     CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3 C.sub.2 H.sub.5 J.sub. 15 -- --     -- O -- H -- CH.sub.3 H CH.sub.3 -- -- -- CH.sub.3 OC.sub.2 H.sub.5     J.sub.15 -- -- -- O -- H -- CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3     CH.sub.2 OCH.sub.3 J.sub.15 -- -- -- O -- H -- CH.sub.3 H CH.sub.3 -- --     -- OCH.sub.3 CH.sub.2 F J.sub.15 -- -- -- O -- H -- CH.sub.3 H CH.sub.3     -- -- -- OCH.sub.3 CF.sub.3 J.sub.15 -- -- -- S -- H -- CH.sub.3 H H --     -- -- OCH.sub.3 OCH.sub.3 J.sub.15 -- -- -- S -- H -- CH.sub.3 H H -- --     -- OCH.sub.3 CH.sub.3 J.sub.15 -- -- -- S -- H -- CH.sub.3 H H -- -- --     CH.sub.3 CH.sub.3 J.sub.15 -- -- -- S -- H -- CH.sub.3 H H -- -- -- Cl     OCH.sub.3 J.sub.15 -- -- -- S -- H -- CH.sub.3 H H -- -- -- Br OCH.sub.3     J.sub.15 -- -- -- S -- H -- H CH.sub.3 CH.sub.3 -- -- -- OCH.sub.3     CH.sub.3 J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H H -- -- --     OCH.sub.3 OCH.sub.3 222-222.5 J.sub.15 -- -- -- SO.sub.2 -- H --     CH.sub.3 H H -- -- -- OCH.sub.3 CH.sub.3 208-209 J.sub.15 -- -- --     SO.sub.2 -- H -- CH.sub.3 H H -- -- -- CH.sub.3 CH.sub.3 192-193     J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H H --  -- -- Cl OCH.sub.3     J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H H -- -- -- Br OCH.sub.3     J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H H -- -- -- OCH.sub.3     C.sub.2 H.sub.5 J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H H -- -- --     CH.sub.3 OC.sub.2 H.sub.5 J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H     H -- -- -- OCH.sub.3 CH.sub.2 OCH.sub.3 J.sub.15 -- -- -- SO.sub.2 -- H     -- CH.sub.3 H H -- -- -- OCH.sub.3 CH.sub.2 F J.sub.15 -- -- -- SO.sub.2     -- H -- CH.sub.3 H H -- -- -- OCH.sub.3 CF.sub.3 J.sub.15 -- -- --     SO.sub.2 -- H -- CH.sub.3 CH.sub.3 H -- -- -- OCH.sub.3 OCH.sub.3     J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3      OCH.sub.3 J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H CH.sub.3 -- --     -- OCH.sub.3 CH.sub.3 J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H     CH.sub.3 -- -- -- CH.sub.3 CH.sub.3 J.sub.15 -- -- -- SO.sub.2 -- H --     CH.sub.3 H CH.sub.3 -- -- -- Cl OCH.sub.3 J.sub.15 -- -- -- SO.sub.2 --     H -- CH.sub.3 H CH.sub.3 -- -- -- Br OCH.sub.3 J.sub.15 -- -- --     SO.sub.2 -- H -- CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3 C.sub.2 H.sub.5     J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H CH.sub.3 -- -- -- CH.sub.3     OC.sub.2 H.sub.5 J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H CH.sub.3     -- -- -- OCH.sub.3 CH.sub.2 OCH.sub.3 J.sub.15 -- -- -- SO.sub.2 -- H --     CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3 CH.sub.2 F J.sub.15 -- -- --     SO.sub.2 -- H -- CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3 CF.sub.3     J.sub.15 -- -- -- SO.sub.2 -- H -- H H H -- -- -- CH.sub.3 CH.sub.3     J.sub.15 -- -- -- SO.sub.2 -- H -- H H H -- -- -- CH.sub.3 OCH.sub.3     J.sub.15 -- -- -- SO.sub.2 -- H -- H H H -- --  -- OCH.sub.3 OCH.sub.3     J.sub.15 -- -- -- SO.sub.2 -- H -- H H H -- -- -- Cl OCH.sub.3 J.sub.15     -- -- -- SO.sub.2 -- 6-Cl CH.sub.3 H H H -- -- -- CH.sub.3 CH.sub.3     J.sub.15 -- -- -- SO.sub.2 -- 6-Cl CH.sub.3 H H H -- -- -- CH.sub.3     OCH.sub.3 J.sub.15 -- -- -- SO.sub.2 -- 6-Cl CH.sub.3 H H H -- -- --     OCH.sub.3 OCH.sub.3 J.sub.15 -- -- -- SO.sub.2 -- 6-Cl CH.sub.3 H H H --     -- -- Cl OCH.sub.3 J.sub.15 -- -- -- S -- H -- CH.sub.3 H CH.sub.3 -- --     -- OCH.sub.3 OCH.sub.3 J.sub.15 -- -- -- S -- H -- CH.sub.3 H CH.sub.3     -- -- -- OCH.sub. 3 CH.sub.3 J.sub.15 -- -- -- S -- H -- CH.sub.3 H     CH.sub.3 -- -- -- CH.sub.3 CH.sub.3 J.sub.15 -- -- -- S -- H -- CH.sub.3     H CH.sub.3 -- -- -- Cl OCH.sub.3 J.sub.15 -- -- -- S -- H -- CH.sub.3 H     CH.sub.3 -- -- -- Br OCH.sub.3 J.sub.15 -- -- -- O -- 6-Cl -- CH.sub.3 H     H -- -- -- OCH.sub.3 OCH.sub.3 J.sub.15 -- -- -- O -- 5-Br -- H H     CH.sub.3 -- -- -- OCH.sub.3 OCH.sub.3 J.sub.15 -- -- -- O -- 6-F --     CH.sub.3 H H -- -- -- OCH.sub.3 OCH.sub.3 J.sub.15 -- -- -- O --     5-CH.sub.3 -- CH.sub.3 H H -- -- -- OCH.sub.3 OCH.sub. 3 J.sub.15 -- --     -- O -- 6-OCH.sub.3 -- CH.sub.3 H H -- -- -- OCH.sub.3 OCH.sub.3     J.sub.15 -- -- -- S -- 6-Cl -- CH.sub.3 H H -- -- -- OCH.sub.3 OCH.sub.3     J.sub.16 -- CH.sub.2 -- O -- H -- CH.sub.3 H -- -- -- -- OCH.sub.3     OCH.sub.3 J.sub.16 -- CH.sub.2 -- S -- H -- H CH.sub.3 -- -- -- --     OCH.sub.3 OCH.sub.3 J.sub.16 -- O -- SO.sub.2 -- H -- CH.sub.3 H -- --     -- -- OCH.sub.3 OCH.sub.3 J.sub.16 -- O -- SO.sub.2 -- H -- CH.sub.3 H     -- -- -- -- Cl OCH.sub.3 J.sub.17 -- -- -- -- O H -- CH.sub.3 H -- -- --     -- OCH.sub.3 OCH.sub.3 J.sub.17 -- -- -- -- S H -- CH.sub.3 H -- -- --     -- OCH.sub.3 OCH.sub.3 J.sub.17 -- -- -- -- O H -- CH.sub.3 CH.sub.3 --     -- -- -- OCH.sub.3 OCH.sub.3 J.sub.17 -- -- -- -- O H -- H H -- -- -- --     OCH.sub.3 OCH.sub.3 J.sub.18 -- CH.sub.2 -- -- -- H -- H H -- H H --     OCH.sub.3 OCH.sub.3 J.sub.18 -- CH.sub.2 -- -- -- H -- H H -- CH.sub.3 H     -- Cl OCH.sub.3 J.sub.18 -- O -- -- -- H -- HH -- H CH.sub.3 -- OCH.sub.3      OCH.sub.3 J.sub.19 -- -- -- -- -- H -- CH.sub.3 CH.sub.3 -- -- -- --     OCH.sub.3 OCH.sub.3 J.sub.19 -- -- -- -- -- H -- H H -- -- -- --     OCH.sub.3 OCH.sub.3 J.sub.19 -- -- -- -- -- H -- H H -- -- -- -- Cl     OCH.sub.3 J.sub.19 -- -- -- -- -- H -- CH.sub.3 CH.sub.3 -- -- -- -- Cl     OCH.sub.3 J.sub.20 -- CH.sub.2 -- -- -- H -- -- -- -- -- -- -- OCH.sub.3     OCH.sub.3 J.sub.20 -- CH.sub.2 -- -- -- H -- -- -- -- -- -- -- OCH.sub.3     CH.sub.3 J.sub.20 -- CH.sub.2 -- -- -- H -- -- -- -- -- -- -- Cl     OCH.sub.3 J.sub.20 -- CH.sub.2 -- -- -- H -- -- -- -- -- -- -- CH.sub.3     CH.sub.3 J.sub.20 -- CH.sub.2 -- -- -- 7-Cl ---- -- -- -- -- -- OCH.sub.3      OCH.sub.3 J.sub.20 -- O -- -- -- H -- -- -- -- -- -- -- OCH.sub.3     OCH.sub.3 J.sub.20 -- O -- -- -- H -- -- -- -- -- -- -- OCH.sub.3     CH.sub.3 J.sub.20 -- O -- -- -- H -- -- -- -- -- -- -- Cl OCH.sub.3     J.sub.20 -- O -- -- -- H -- -- -- -- -- -- -- CH.sub.3 CH.sub.3 J.sub.21     -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- F OCH.sub.3 OCH.sub.3 J.sub.21     -- CH.sub.2 -- -- -- --  -- -- -- -- -- -- Cl Cl OCH.sub.3 J.sub.21 --     CH.sub.2 -- -- -- -- -- -- -- -- -- -- Br OCH.sub.3 CH.sub.3 J.sub.21 --     CH.sub.2 -- -- -- -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 OCH.sub.3     J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- SCH.sub.3 OCH.sub.3     OCH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- SO.sub.2     CH.sub.3 OCH.sub.3 OCH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- --     -- -- -- CO.sub.2 CH.sub.3 OCH.sub.3 OCH.sub.3 J.sub.21 -- CH.sub.2 --     -- -- -- -- -- -- -- -- -- CO.sub.2 CH.sub.3 OCH.sub.3 OCH.sub.3     J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- SO.sub.2      N(CH.sub.3).sub.2 OCH.sub.3 OCH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- --     -- -- -- -- -- -- OSO.sub.2 CH.sub.3 OCH.sub.3 OCH.sub.3 J.sub.21 --     CH.sub.2 -- -- -- -- -- -- -- -- -- -- Cl OCH.sub.3 OCH.sub.3 J.sub.21     -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- Cl Br OCH.sub.3 J.sub.21 --     CH.sub.2 -- -- -- -- -- -- -- -- -- -- Cl OCH.sub.2 CH.sub.2 F J.sub.21     -- CH.sub.2 -- -- -- -- -- -- -- -- --  -- Cl CH.sub.3 OC.sub.2 H.sub.5     J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- Cl OCH.sub.3 C.sub.2     H.sub.5 J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- F OCH.sub.3 OCH.sub.3      J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- Cl OCH.sub.3 OCH.sub.3     J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- Br Cl OCH.sub.3 J.sub.21 --     O -- -- -- -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 OCH.sub.3 J.sub.21     -- O -- -- -- -- -- -- -- -- -- -- SCH.sub.3 OCH.sub.3 OCH.sub.3     J.sub.21 -- O --  -- -- -- -- -- -- -- -- -- SO.sub.2 CH.sub.3 OCH.sub.3     OCH.sub.3 J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- CO.sub.2 CH.sub.3     OCH.sub.3 OCH.sub.3 J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- SO.sub.2     N(CH.sub.3).sub.2 OCH.sub.3 OCH.sub.3 J.sub.21 -- O -- -- -- -- -- -- --     -- -- -- OSO.sub.2 CH.sub.3 OCH.sub.3 CH.sub.3 J.sub.21 -- CH.sub.2 --     -- -- -- -- -- -- -- -- -- CO.sub.2 CH.sub.3 CH.sub.3 OCH.sub.3 J.sub.21     -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- CO.sub.2 CH.sub.3 CH.sub.3     CH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- CO.sub.2     CH.sub.3 Cl OCH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- --     CO.sub.2 CH.sub.3 Br OCH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- --     -- -- -- CO.sub.2 CH.sub.3 OCH.sub.3 C.sub.2 H.sub.5 J.sub.21 --     CH.sub.2 -- -- -- -- -- -- -- -- -- -- CO.sub.2 CH.sub.3 CH.sub.3     OC.sub.2 H.sub.5 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- --     CO.sub.2 CH.sub.3 OCH.sub.3 CH.sub.2 F J.sub.21 -- CH.sub.2 -- -- -- --     -- -- -- -- -- -- CO.sub.2 CH.sub.3 OCH.sub. 3 CF.sub.3 J.sub.4 0     CH.sub.2 -- -- -- H -- H H -- -- -- -- OCH.sub.3 CH.sub.2 CH.sub.2     CH.sub.3 J.sub.4 0 CH.sub.2 -- -- -- H -- H H -- -- -- -- Cl NHCH.sub.3     J.sub.4 0 CH.sub.2 -- -- -- H -- H H -- -- -- -- Cl OCF.sub.2 H J.sub.4     0 CH.sub.2 -- -- -- H -- H H -- -- -- -- Cl N(CH.sub.3).sub.2 J.sub.4 0     CH.sub.2 -- -- -- H -- H H -- -- -- -- OCH.sub.3 cyclopropyl J.sub.4 0     CH.sub.2 -- -- -- H -- H H -- -- -- -- OCH.sub.3 C.tbd.CH J.sub.4 0     CH.sub.2 -- -- -- H -- H H -- -- -- -- OCH.sub. 3 OCH.sub.2      CH═CH.sub.2 J.sub.4 0 CH.sub.2 -- -- -- H -- H H -- -- -- --     OCH.sub.3 OCH.sub.2 CH.sub.2 F J.sub.5 0 -- -- -- -- H CH.sub.3 -- -- --     -- -- -- OCH.sub.3 CH(CH.sub.3).sub.2 J.sub.5 0 -- -- -- -- H CH.sub.3     -- -- -- -- -- -- Cl NHCH.sub.3 J.sub.5 0 -- -- -- -- H CH.sub.3 -- --     -- -- -- -- Cl OCF.sub.2 H J.sub.5 0 -- -- -- -- H CH.sub.3 -- -- -- --     -- -- Cl N(CH.sub.3).sub.2 J.sub.5 0 -- -- -- -- H CH.sub.3 -- -- -- --     -- -- OCH.sub.3 cyclopropyl J.sub.5 0 -- -- -- -- H CH.sub.3 -- -- -- --     -- -- OCH.sub.3 C.tbd.CH J.sub.5 0 -- -- -- -- H CH.sub.3 -- -- -- -- --     -- OCH.sub.3 OCH.sub.2 C.tbd.CH J.sub.5 0 -- -- -- -- H CH.sub.3 -- --     -- -- -- -- OCH.sub.3 OCH.sub.2 CH.sub.2 F J.sub.5 0 -- -- -- -- H     CH.sub.3 -- -- -- -- -- -- Cl OCF.sub.2 H J.sub.5 0 -- -- -- -- H     CH.sub.3 -- -- -- -- -- -- OCH.sub.3 SCH.sub.3 J.sub.5 0 -- -- -- -- H     CH.sub.3 -- -- -- -- -- -- OCH.sub.3 CH(OCH.sub.3).sub.2 J.sub.5 0 -- --     -- -- H CH.sub.3 -- -- -- -- -- --  OCH.sub.3 1,3-dioxolan-       2-yl J.sub.6 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3      CH(CH.sub.3).sub.2 J.sub.6 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- --     -- -- OCH.sub.3 cyclopropyl J.sub.6 0 CH.sub.2 -- -- -- H CH.sub.3 -- --     -- -- -- -- OCH.sub.3 C.tbd.CH J.sub.6 0 CH.sub.2 -- -- -- H CH.sub.3 --     -- -- -- -- -- Cl N(CH.sub.3).sub.2 J.sub.6 0 CH.sub.2 -- -- -- H     CH.sub.3 -- -- -- -- -- -- Cl N(CH.sub.3).sub.2 J.sub.6 0 CH.sub.2 -- --     -- H CH.sub.3 -- -- -- -- -- -- OCH.sub. 3 OCH.sub.2 CH.sub.2 F J.sub.6     0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 SCH.sub.3     J.sub.6 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3     CH(OCH.sub.3).sub.2 J.sub.8 -- CH.sub.2 -- -- -- H -- -- -- -- -- -- --     OCH.sub.3 NHCH.sub.3 J.sub.8 -- CH.sub.2 -- -- -- H -- -- -- -- -- -- --     OCH.sub.3 C.tbd.CH J.sub.8 -- CH.sub.2 -- -- -- H -- -- -- -- -- -- --     Cl NHCH.sub.3 J.sub.8 -- CH.sub.2 -- -- -- H -- -- -- -- -- -- --     OCH.sub.3 CH(OCH.sub.3).sub.2 J.sub.8 -- CH.sub.2 --  -- -- H -- -- --     -- -- -- -- OCH.sub.3 OCH.sub.2 C.tbd.CH J.sub.8 -- CH.sub.2 -- -- -- H     -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.2 CH.sub.2 F J.sub.8 -- CH.sub.2     -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 SCH.sub.3 J.sub.8 -- CH.sub.2     -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 1,3-dioxolan-     2-yl J.sub.8 -- CH.sub.2 -- -- -- H -- -- -- -- -- -- -- OCH.sub.3     cyclopropyl J.sub.9 -- O -- -- -- H -- -- -- -- -- -- -- OCH.sub.3     CH(OCH.sub.3).sub.2 J.sub. 9 -- O -- -- -- H -- -- -- -- -- -- -- Cl     N(CH.sub.3).sub.2 J.sub.9 -- O -- -- -- H -- -- -- -- -- -- -- OCH.sub.3     NHCH.sub.3 J.sub.10 -- -- -- -- -- H CH.sub.3 -- -- -- -- -- -- Cl     NHCH.sub.3 J.sub.10 -- -- -- -- -- H CH.sub.3 -- -- -- -- -- -- Cl     OCH.sub.3 J.sub.11 -- -- -- -- -- H CH.sub.3 -- -- -- -- -- -- Cl     OCH.sub.3 J.sub.11 -- -- -- -- -- H -- -- -- -- -- -- -- OCH.sub.3     NHCH.sub.3 J.sub.12 -- O -- -- -- H -- -- -- --  -- -- -- Cl NHCH.sub.3     J.sub.12 -- O -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 N(CH.sub.3).sub.2      J.sub.12 -- O -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 1,3-dioxolan-                  2-yl J.sub.13 -- CH.sub.2 CH.sub.2 -- -- H -- -- -- -- --     -- -- OCH.sub.3 NHCH.sub.3 J.sub.13 -- CH.sub.2 CH.sub.2 -- -- H -- --     -- -- -- -- -- OCH.sub.3 SHC.sub.3 J.sub.13 -- CH.sub.2 CH.sub.2 -- -- H     -- -- -- -- -- -- -- OCH.sub.3 CH(OCH.sub.3).sub.2 J.sub.13 -- CH.sub.2     CH.sub.2 -- -- H -- -- --  -- -- -- -- OCH.sub.3 OCH.sub.2 CH.tbd.CH     J.sub.14 -- CH.sub.2 -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.2     CH═CH.sub.2 J.sub.14 -- CH.sub.2 -- -- -- H -- -- -- -- -- -- --     CH.sub.3 OCH.sub.2 CH.sub.2 F J.sub.14 -- CH.sub.2 -- -- -- H -- -- --     -- -- -- -- OCH.sub.2 CF.sub.3 OCH.sub.3 J.sub.14 -- CH.sub.2 -- -- -- H     -- -- -- -- -- -- -- OCHF.sub.2 OCHF.sub.2 J.sub.14 -- CH.sub.2 -- -- --     H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.2 CH.sub.2 OCH.sub.3 J.sub.15     -- -- -- O -- H -- CH.sub.3 H H -- -- -- OCH.sub.3 NHCH.sub.3 J.sub.15     -- -- -- O -- H -- CH.sub.3 H H -- -- -- OCH.sub.3 OCH.sub.2      CH═CH.sub.2 J.sub.15 -- -- -- O -- H -- H H H -- -- -- OCH.sub.3     C.tbd.CH J.sub.15 -- -- -- O -- H -- H H H -- -- -- OCH.sub.3 OCH.sub.2     CH.sub.2 F J.sub.15 -- -- -- O -- H -- CH.sub.3 H H -- -- -- OCH.sub.3     OCH.sub.2 CH═CHCl J.sub.15 -- -- -- O -- H -- H H H -- -- -- Cl     NHCH.sub.3 J.sub.15 -- -- -- O -- H -- H H CH.sub.3 -- -- -- Cl N(CH.sub.     3).sub.2 J.sub.15 -- -- -- O -- H -- H H CH.sub. 3 -- -- -- OCH.sub.3     cyclopropyl J.sub.15 -- -- -- O -- H -- H H CH.sub.3 -- -- -- OCH.sub.3     CH(OCH.sub.3).sub.2 J.sub.15 -- -- -- O -- H -- CH.sub.3 CH.sub.3 H --     -- -- OCH.sub.3 NHCH.sub.3 J.sub.15 -- -- -- O -- H -- CH.sub.3 CH.sub.3     H -- -- -- OCH.sub.3 CH(OCH.sub.3).sub.2 J.sub.15 -- -- -- O -- H --     CH.sub.3 H H -- -- -- OCH.sub.3 OCH.sub.2 C.tbd.CH J.sub.15 -- -- -- O     -- H -- CH.sub.3 CH.sub.3 H -- -- -- OCH.sub.3 SCH.sub.3 J.sub.15 -- --     -- S -- H -- CH.sub.3 H H -- -- -- OCH.sub.3 NHCH.sub.3 J.sub.15 -- --     -- S -- H --  CH.sub.3 H H -- -- -- OCH.sub.3 N(CH.sub.3).sub.2 J.sub.15     -- -- -- S -- H -- CH.sub.3 H H -- -- -- OCH.sub.3 OCH.sub.2      CH═CH.sub.2 J.sub.15 -- -- -- S -- H -- CH.sub.3 H H -- -- --     OCH.sub.3 cyclopropyl J.sub.15 -- -- -- S -- H -- CH.sub.3 H H -- -- --     Cl N(CH.sub.3).sub.2 J.sub.15 -- -- -- S -- H -- CH.sub.3 CH.sub.3     CH.sub.3 -- -- -- OCH.sub.3 CH(OCH.sub.3).sub.2 J.sub.15 -- -- --     SO.sub.2 -- H -- CH.sub.3 H H -- -- -- OCH.sub.3 NHCH.sub.3 J.sub.15 --     -- -- SO.sub.2 -- H -- CH.sub.3 H H -- -- -- Cl.sub.3 N(CH.sub.2)     J.sub.15 -- --  -- SO.sub.2 -- H -- CH.sub.3 H H -- -- -- OCH.sub.3     OCH.sub.2 CH═CH.sub.2 J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H     H -- -- -- OCHF.sub.2 SCH.sub.3 J.sub.15 -- -- -- SO.sub.2 -- H --     CH.sub.3 H H -- -- -- CH.sub.3 OCH.sub.2 CH.sub.2 OCH.sub.3 J.sub.15 --     -- -- SO.sub.2 -- H -- CH.sub.3 H H -- -- -- CH.sub.3 CH(OCH.sub.3).sub.2      J.sub.16 -- CH.sub.2 -- O -- H -- CH.sub.3 H -- -- -- -- OCH.sub.3     N(CH.sub.3).sub.2 J.sub.16 -- CH.sub.2 -- S -- H -- H CH.sub.3 -- -- --     -- OCH.sub.3 OCH.sub.2 CH═CH.sub.2 J.sub.16 -- O -- SO.sub.2 -- H --     CH.sub.3 H -- -- -- -- OCH.sub.3 OCH.sub.2 CH.sub.2 F J.sub.16 -- O --     SO.sub.2 -- H -- CH.sub.3 H -- -- -- -- OCH.sub.3 OCH.sub.2 CH.sub.2     OCH.sub.3 J.sub.17 -- -- -- -- O H -- CH.sub.3 H -- -- -- -- Cl N(CH.sub.     3).sub.2 J.sub.17 -- -- -- -- O H -- CH.sub.3 H -- -- -- -- CH.sub.3     CH(OCH.sub.3).sub.2 J.sub.17 -- -- -- -- S H -- CH.sub.3 H -- -- -- --     OCH.sub.3 NHCH.sub.3 J.sub.18 -- CH.sub.2 -- -- -- H -- H H -- H H --     OCH.sub.3 NHCH.sub.3 J.sub.18 -- CH.sub.2 -- -- -- H -- H H -- CH.sub.3     H -- Cl N(CH.sub.3).sub.2 J.sub.18 -- O --  -- -- H -- H H -- H CH.sub.3     -- CH.sub.3 OCH.sub.2 CH.sub.2 OCH.sub.3 J.sub.19 -- -- -- -- -- H -- H     H -- -- -- -- CH.sub.3 OCH.sub.2 CH.sub.2 F J.sub.19 -- -- -- -- -- H --     CH.sub.3 CH.sub.3 -- -- -- -- OCH.sub.3 NHCH.sub.3 J.sub.19 -- -- -- --     -- H -- H CH.sub.3 -- -- -- -- OCH.sub.3 C.tbd.CH J.sub.20 -- CH.sub.2     -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 NHCH.sub.3 J.sub.20 --     CH.sub.2 -- -- -- H -- -- -- -- -- -- -- CH.sub.3 OCH.sub.2 CH.sub.2 F     J.sub.20 -- O -- -- -- H -- -- --  -- -- -- -- OCH.sub.3 C.tbd.CH     J.sub.20 -- O -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 CH(OCH.sub.3).sub     .2 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- Cl OCH.sub.3     NHCH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- Br     OCH.sub.3 N(CH.sub.3).sub.2 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- --     -- -- F OCH.sub.3 NHCH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- --     -- -- -- OCH.sub.3 OCH.sub.3 NHCH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- --     -- -- -- -- -- -- SO.sub.2 N(CH.sub.3).sub.2 OCH.sub.3 C.tbd.CH J.sub.21     -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- Cl OCH.sub.3 OCH.sub.2     CH.sub.2 F J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- Cl Cl NHCH.sub.3     J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- Br OCH.sub.3 NHCH.sub.3     J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 NHCH.sub.     3 J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- SO.sub.2 N(CH.sub.3).sub.2     OCH.sub.3 NHCH.sub.3 J.sub.21 -- O -- -- -- -- -- -- -- -- -- --     SO.sub.2 CH.sub.3 OCH.sub.3 NHCH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- --     -- -- -- -- -- -- CO.sub.2 CH.sub.3 OCH.sub.3 OCH.sub.3 148-151.5     J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- CO.sub.2 CH.sub.3     CH.sub.3 CH.sub.3 191-193.5 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- --     -- -- CO.sub.2      CH.sub.3 OCH.sub.3 CH.sub.3

                                      TABLE 2                                     __________________________________________________________________________    General Formula 2                                                                                                     m.p.                                  J n L  R.sub.1                                                                            R.sub.9      X     Y        (°C.)                          __________________________________________________________________________    J.sub.1                                                                         0 CH.sub.2                                                                         H    CH.sub.3     CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    CH.sub.3     CH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                         0 CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           C.sub.2 H.sub.5                                J.sub.1                                                                         0 CH.sub.2                                                                         H    CH.sub.3     CH.sub.3                                                                            OC.sub.2 H.sub.5                               J.sub.1                                                                         0 CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           CH.sub.2 OCH.sub.3                             J.sub.1                                                                         0 CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           CH.sub.2 F                                     J.sub.1                                                                         0 CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           CF.sub.3                                       J.sub.1                                                                         1 CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           CH.sub.3                                       J.sub.1                                                                         0 CH.sub.2                                                                         H    C.sub.2 H.sub.5                                                                            OCH.sub.3                                                                           CH.sub.3                                       J.sub.1                                                                         0 CH.sub.2                                                                         H    n-C.sub.3 H.sub.7                                                                          OCH.sub.3                                                                           CH.sub.3                                       J.sub.1                                                                         0 CH.sub.2                                                                         H    CH(CH.sub.3).sub.2                                                                         OCH.sub.3                                                                           CH.sub.3                                       J.sub.1                                                                         0 CH.sub.2                                                                         H    H            OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    H            OCH.sub.3                                                                           CH.sub.3                                       J.sub.1                                                                         0 CH.sub.2                                                                         H    H            CH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                         0 O  H    H            CH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                         0 O  H    H            CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 O  H    H            OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 O  H    CH.sub.3     CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 O  H    CH.sub.3     CH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                         0 O  H    C.sub.2 H.sub.5                                                                            OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 O  H    n-C.sub.3 H.sub.7                                                                          OCH.sub.3                                                                           CH.sub.3                                       J.sub.1                                                                         0 O  H    CH(CH.sub.3).sub.2                                                                         OCH.sub.3                                                                           CH.sub.3                                       J.sub.1                                                                         1 O  H    CH.sub.3     OCH.sub.3                                                                           CH.sub.3                                       J.sub.1                                                                         0 CH.sub.2                                                                         5-F  CH.sub.3     OCH.sub.3                                                                           CH.sub.3                                       J.sub.1                                                                         0 CH.sub.2                                                                         6-Cl CH.sub.3     OCH.sub.3                                                                           CH.sub.3                                       J.sub.1                                                                         0 CH.sub.2                                                                         6-Br CH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         6-CH.sub.3                                                                         CH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         6-OCH.sub.3                                                                        CH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.2 CF.sub.3                                                                  CH.sub.3                                       J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           CH(CH.sub.3)                                   J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           cyclopropyl                                    J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           C.tbd.CH                                       J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           NH.sub.2                                       J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           N(CH.sub.3).sub.2                              J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           OCH.sub.2 CH.sub.2 F                           J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           SCH.sub.3                                      J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           OCH.sub.2 CH═CH.sub.2                      J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           OCH.sub.2 CH.sub.2 OCH.sub.3                   J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           OCH.sub.2 C.tbd.CH                             J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           CH(OCH.sub.3).sub.2                            J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           C(CH.sub.3)(OCH.sub.3).sub.2                   J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           1,3-dioxolan-                                                                 2-yl                                           J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub. 3                                                                          2-methyl-1,3-                                                                 dioxolan-2-yl                                  J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           CH(OC.sub.2 H.sub.5).sub.2                     J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           C(CH.sub.3)(OC.sub.2 H.sub.5).sub.2            J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           NHCH.sub.3                                     J.sub.1                                                                         0 O  H    --CH.sub.2 CN                                                                              OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 O  H    --(CH.sub.2).sub.3 CN                                                                      CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    OH           CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --(CH.sub.2).sub.3 CH(CH.sub.3).sub.2                                                      Cl    OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CF.sub.2 H OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CH.sub.2 CH.sub.2 Cl                                                                     Cl    OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --(CH.sub.2).sub.5 Cl                                                                      CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CH.sub.2 OCH.sub.3                                                                       Cl    OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --(CH.sub.2).sub.4 OCH.sub.3                                                               CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CH.sub.2 CH═CH.sub.2                                                                 OCH.sub.3                                                                           OCH.sub. 3                                     J.sub.1                                                                         0 CH.sub.2                                                                         H    --CH.sub.2 CH═CHCH.sub.3                                                               CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CH.sub.2 C.tbd.CH                                                                        OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --(CH.sub.2).sub.4 C.tbd.CH                                                                CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --OCH.sub.3  CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --C.sub.6 H.sub.5                                                                          CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    cyclopropyl  OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    cyclohexyl   OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    cyclopropylmethyl                                                                          OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    cyclohexylmethyl                                                                           CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --C(O)CH.sub.3                                                                             OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --C(O)(CH.sub.2).sub.5 H                                                                   OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CO.sub.2 C.sub.2 H.sub.5                                                                 CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CO.sub.2 (CH.sub.2).sub.4 H                                                              CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CH.sub.2 C.sub.6 H.sub.5                                                                 OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CH.sub.2 --CH═CH--CH.sub.2 Cl                                                        CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CH.sub.2 C.tbd.C--CH.sub.2 Cl                                                            CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CH.sub.2 C(O)CH.sub.3                                                                    OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                     OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    H            OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    H            CH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                         0 O  H    H            CH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                         0 O  H    H            OCH.sub.3                                                                           CH.sub.3                                       J.sub.1                                                                         0 O  H    H            OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    n-C.sub.4 H.sub.9                                                                          CH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                         0 CH.sub.2                                                                         H    n-C.sub.4 H.sub.9                                                                          CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    n-C.sub.4 H.sub.9                                                                          OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 O  H    n-C.sub.4 H.sub.9                                                                          CH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                         0 O  H    n-C.sub.4 H.sub.9                                                                          OCH.sub.3                                                                           CH.sub.3                                       J.sub.1                                                                         0 O  H    n-C.sub.4 H.sub.9                                                                          OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    n-C.sub.3 H.sub.7                                                                          CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH(CH.sub.3).sub.2                                                                         CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              O  H    CH.sub.3     CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         7-Cl CH.sub.3     CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              O  7-Br CH.sub.3     CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         6-F  CH.sub.3     CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              O  7-CH.sub.3                                                                         CH.sub.3     CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              O  7-OCH.sub.3                                                                        CH.sub.3     CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           CH.sub.3                                       J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     CH.sub.3                                                                            CH.sub.3                                       J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           C.sub.2 H.sub.5                                J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     CH.sub.3                                                                            OC.sub.2 H.sub.5                               J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           CH.sub.2 OCH.sub.3                             J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           CH.sub.2 F                                     J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           CF.sub.3                                       J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    H            CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    C.sub.2 H.sub.5                                                                            CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.2 CF.sub.3                                                                  OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           cyclopropyl                                    J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           NHCH.sub.3                                     J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           N(CH.sub.3).sub.2                              J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           OCH.sub.2 CH═CH.sub.2                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           CH(OCH.sub.3).sub.2                            J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           1,3-dioxolan-                                                                 2-yl                                           J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           CH(OC.sub.2 H.sub.5).sub.2                     J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           --C.tbd.CH                                     J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           C(CH.sub.3)(OCH.sub. 3).sub.2                  J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    OH           OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    (CH.sub.2).sub.2 CH(CH.sub.3)                                                              CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.2 CH.sub.2 Cl                                                                       OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    (CH.sub.2).sub.5 Cl                                                                        CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.2 OCH.sub.3                                                                         CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    (CH.sub.2).sub.2 OCH.sub.3                                                                 CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.2 CH═CH.sub.2                                                                   OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.2 CH═CHCH.sub.2 Cl                                                              CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.2 CH═CHCH.sub.3                                                                 CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.2 C.tbd.OCH.sub.3                                                                   OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    OCH.sub.3    OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    O(CH.sub.2).sub.4 CH.sub.3                                                                 CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    C.sub. 6 H.sub.5                                                                           OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    cyclopropyl  CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    cyclopentyl  OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    COCH.sub.3   OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.2 C.sub.6 H.sub.5                                                                   CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.2 CH═CHCl                                                                       CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH(CH.sub.3)CO.sub.2 CH.sub.3                                                              CH.sub.3                                                                            OCH.sub.3                                      __________________________________________________________________________

    TABLE 2a      General Formula 2a                 m.p. J n L Q Q.sub.1 Q.sub.2 R.sub.1     R.sub.2 R.sub.3 R.sub.4 R.sub.5 R.sub.6 R.sub.7 R.sub.8 X Y (°C.)       J.sub.2 0 CH.sub.2 -- -- -- H -- H CH.sub.3 -- -- -- -- OCH.sub.3     OCH.sub.3  J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- --     OCH.sub.3 CH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- --     -- OCH.sub.3 C.sub.2 H.sub.5 J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 --     -- -- -- -- -- CH.sub.3 OC.sub.2 H.sub.5 J.sub.2 0 CH.sub.2 -- -- -- H     CH.sub.3 -- -- -- -- -- -- OCH.sub.3 CH.sub.2 OCH.sub.3 J.sub.2 0     CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 CH.sub.2 F     J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3     CF.sub.3 J.sub.2 0 CH.sub.2 -- -- -- H H -- -- -- -- -- -- CH.sub.3     OCH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- H C.sub.2 H.sub.5 -- -- -- -- --     -- CH.sub.3 OCH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- H n-C.sub.3 H.sub.7 --     -- -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- H CH(CH.sub     .3).sub.2 -- -- -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.2 1 CH.sub.2 -- --     -- H CH.sub.3 -- -- -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.2 0 O -- -- --     H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.2 0 O -- -- -- H     CH.sub.3 -- -- -- -- -- -- OCH.sub.3 CH.sub.3 J.sub.2 1 O -- -- -- H     CH.sub.3 -- -- -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.2 0 O -- -- -- H     C.sub.2 H.sub.5 -- -- -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.2 0 CH.sub.2     -- -- -- 6-Br CH.sub.3 -- -- -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.2 0     CH.sub.2 -- -- -- 6-Cl CH.sub.3 -- -- -- -- -- -- CH.sub.3 OCH.sub.3     J.sub.2 0 CH.sub.2 -- -- -- 5-F CH.sub.3 -- -- -- -- -- -- CH.sub.3     OCH.sub.3 J.sub.2 0 O -- -- -- 6-CH.sub.3 CH.sub.3 -- -- -- -- -- --     CH.sub.3 OCH.sub.3 J.sub.2 0 O -- -- -- 6-OCH.sub.3 CH.sub.3 -- -- -- --     -- -- CH.sub.3 OCH.sub.3 J.sub.3 0 CH.sub.2 -- -- -- H -- H H -- -- --     -- OCH.sub.3 OCH.sub.3 J.sub.3 0 CH.sub.2 -- -- -- H -- H H -- -- -- --     CH.sub.3 OCH.sub.3 175-183,d J.sub.3 0 CH.sub.2 -- -- -- H -- H H -- --     -- -- CH.sub.3 CH.sub.3 J.sub.3 0 CH.sub.2 -- -- -- H -- H H -- -- -- --     OCH.sub.3 C.sub.2 H.sub.5 J.sub.3 0 CH.sub.2 -- -- -- H -- H H -- -- --     -- CH.sub.3 OC.sub.2 H.sub.5 J.sub.3 0 CH.sub.2 -- -- -- H -- H H -- --     -- -- CH.sub.3 CH.sub.2 OCH.sub.3 J.sub.3 0 CH.sub.2 -- -- -- H -- H H     -- -- -- -- OCH.sub.3 CH.sub.2 F J.sub.3 0 CH.sub.2 -- -- -- H -- H H --     -- -- -- OCH.sub.3 CF.sub.3 J.sub.3 1 CH.sub.2 -- -- -- H -- H H -- --     -- -- CH.sub.3 OCH.sub.3 J.sub.3 0 CH.sub.2 -- -- -- H -- CH.sub.3 H --     -- -- -- CH.sub.3 OCH.sub.3 J.sub.3 0 CH.sub.2 -- -- -- H -- H CH.sub.3     -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.3 0 O -- -- -- H -- H H -- -- -- --     OCH.sub.3 OCH.sub.3 J.sub.3 0 O -- -- -- H -- H H -- -- -- -- CH.sub.3     CH.sub.3 J.sub.3 0 O -- -- -- H -- H H -- -- -- -- OCH.sub.3 CH.sub.3     J.sub.3 0 O -- -- -- H -- H H -- -- -- -- CH.sub.3 CH.sub.3 J.sub.3 0     CH.sub.2 -- -- -- 5-F -- H H -- -- -- -- CH.sub.3 OCH.sub. J.sub.3 0     CH.sub.2 -- -- -- 6-Cl -- H H -- --  -- -- OCH.sub.3 OCH.sub.3 J.sub.3 0     CH.sub.2 -- -- -- 6-Br -- H H -- -- -- -- OCH.sub.3 CH.sub.3 J.sub.3 0 O     -- -- -- 5-CH.sub.3 -- H H -- -- -- -- OCH.sub.3 CH.sub.3 J.sub.3 0 O --     -- -- 6-OCH.sub.3 -- H H -- -- -- -- OCH.sub.3 CH.sub.3 J.sub.3 1 O --     -- -- H -- H H -- -- -- -- OCH.sub.3 CH.sub.3 J.sub.3 1 CH.sub.2 -- --     -- H -- CH.sub.3 H -- -- -- -- CH.sub.3 CH.sub.3 J.sub.3 1 CH.sub.2 --     -- -- H -- CH.sub.3 H -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.3 1 CH.sub.2     -- -- -- H -- CH.sub.3 H -- -- --  -- OCH.sub.3 OCH.sub.3 J.sub.3 1 O --     -- -- H -- CH.sub.3 H -- -- -- -- CH.sub.3 CH.sub.3 J.sub.3 1 O -- -- --     H -- CH.sub.3 H -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.3 1 O -- -- -- H --     CH.sub.3 H -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.4 0 CH.sub.3 -- -- -- H     -- -- -- -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.4 1 CH.sub.2 -- -- -- H --     -- -- -- -- -- -- CH.sub.3 CH.sub.3 J.sub.4 0 O -- -- -- H -- -- -- --     -- -- -- CH.sub.3 OCH.sub.3 J.sub.4 1 O -- -- -- H -- -- -- -- --  -- --     CH.sub.3 OCH.sub.3 J.sub.5 0 -- -- -- -- H CH.sub.3 -- -- -- -- -- --     OCH.sub.3 OCH.sub.3 J.sub.5 0 -- -- -- -- H CH.sub.3 -- -- -- -- -- --     CH.sub.3 OCH.sub.3 J.sub.5 0 -- -- -- -- H CH.sub.3 -- -- -- -- -- --     CH.sub.3 CH.sub.3 J.sub.5 1 -- -- -- -- H CH.sub.3 -- -- -- -- -- --     CH.sub.3 OCH.sub.3 J.sub.5 0 -- -- -- -- H H -- -- -- -- -- -- CH.sub.3     OCH.sub.3 J.sub.6 0 -- -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3     OCH.sub.3 J.sub.6 0 -- -- -- -- H CH.sub.3 -- -- -- -- -- -- CH.sub.3     OCH.sub.3 J.sub.6 0 -- -- -- -- H H -- -- -- -- -- -- CH.sub.3 OCH.sub.3     J.sub.6 1 -- -- -- -- H CH.sub.3 -- -- -- -- -- -- CH.sub.3 OCH.sub.3     J.sub.8 -- CH.sub.2 -- -- -- H -- H -- -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.8 -- CH.sub.2 -- -- -- H -- H -- -- -- -- -- OCH.sub.3 CH.sub.3     J.sub.8 -- CH.sub.2 -- -- -- H -- CH.sub.3 -- -- -- -- -- OCH.sub.3     CH.sub.3 J.sub.8 -- CH.sub.2 -- -- -- H -- H -- -- -- -- -- OCH.sub.3     C.sub.2 H.sub.5 J.sub.8 -- CH.sub.2 -- -- -- H -- H -- -- -- -- --     CH.sub.3 OC.sub.2 H.sub.5 J.sub.8 -- CH.sub.2 -- -- -- H -- H -- -- --     -- -- OCH.sub.3 CH.sub.2 OCH.sub.3 J.sub.8 -- CH.sub.2 -- -- -- H -- H     -- -- -- -- -- OCH.sub.3 CH.sub.2 F J.sub.8 -- CH.sub.2 -- -- -- H -- H     -- -- -- -- -- OCH.sub.3 CF.sub.3 J.sub.8 -- O -- -- -- H -- H -- -- --     -- -- OCH.sub.3 OCH.sub.3 J.sub.8 -- O -- -- -- H -- H -- -- -- -- --     OCH.sub.3 CH.sub.3 J.sub.8 -- CH.sub.2 -- -- -- 7-Cl -- H --  -- -- --     -- CH.sub.3 OCH.sub.3 J.sub.9 -- CH.sub.2 -- -- -- H -- -- -- -- -- --     -- OCH.sub.3 OCH.sub.3 J.sub.9 -- CH.sub.2 -- -- -- H -- -- -- -- -- --     -- OCH.sub.3 CH.sub.3 J.sub.9 -- O -- -- -- H -- -- -- -- -- -- --     CH.sub.3 OCH.sub.3 J.sub.10 -- -- -- -- -- H CH.sub.3 -- -- -- -- -- --     OCH.sub.3 OCH.sub.3 J.sub.10 -- -- -- -- -- H CH.sub.3 -- -- -- -- -- --     OCH.sub.3 CH.sub.3 J.sub.10 -- -- -- -- -- H C.sub.2 H.sub.5 -- -- -- --     -- -- CH.sub.3 OCH.sub.3 J.sub.11 -- -- -- -- -- H CH.sub.3 -- -- -- --     -- -- CH.sub.3 OCH.sub.3 J.sub.11 -- -- -- -- -- H C.sub.2 H.sub.5 -- --     -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.12 -- CH.sub.2 -- -- -- H -- H --     -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.12 -- CH.sub.2 -- -- -- H -- H --     -- -- -- -- OCH.sub.3 CH.sub.3 J.sub.12 -- CH.sub.2 -- -- -- H --     CH.sub.3 -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.12 -- CH.sub.2 -- --     -- H -- CH.sub.3 -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.12 -- O -- --     -- H -- H -- -- -- -- -- OCH.sub.3 CH.sub.3 J.sub.12 -- O -- -- -- H --     CH.sub.3 -- -- -- -- -- OCH.sub.3 CH.sub.3 J.sub.13 -- CH.sub.2 O -- --     H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.13 -- CH.sub.2 O -- --     H -- -- -- -- -- -- -- OCH.sub.3 CH.sub.3 J.sub.13 -- O O -- -- H -- --     -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.13 -- O O -- -- H -- -- -- --     -- -- -- OCH.sub.3 CH.sub.3 J.sub.13 -- CH.sub.2 CH.sub.2 -- -- H -- --     -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.13 -- CH.sub.2 CH.sub. 2 -- --     H -- -- -- -- -- -- -- OCH.sub.3 CH.sub.3 J.sub.13 -- O CH.sub.2 -- -- H     -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.13 -- O CH.sub.2 -- -- H     -- -- -- -- -- -- -- OCH.sub.3 O CH.sub.3 J.sub.14 -- CH.sub.2 -- -- --     H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.14 -- CH.sub.2 -- -- --     H -- -- -- -- -- -- -- OCH.sub.3 CH.sub.3 J.sub.14 -- O -- -- -- H -- --     -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.14 -- O -- -- -- H -- -- -- --     -- -- -- OCH.sub.3 CH.sub.3 J.sub.15 -- -- -- O -- H -- CH.sub.3 H H --     -- -- OCH.sub.3 OCH.sub.3 J.sub.15 -- -- -- O -- H -- CH.sub.3 H H -- --     -- OCH.sub.3 CH.sub.3 J.sub.15 -- -- -- O -- H -- H H CH.sub.3 -- -- --     CH.sub.3 CH.sub.3 J.sub.15 -- -- -- O -- H -- H H CH.sub.3 -- -- --     OCH.sub.3 C.sub.2 H.sub.5 J.sub.15 -- -- -- O -- H -- CH.sub.3 H H -- --     -- CH.sub.3 OC.sub.2 H.sub.5 J.sub.15 -- -- -- O -- H -- CH.sub.3 H H --     -- -- OCH.sub.3 CH.sub.2 OCH.sub.3 J.sub.15 -- -- -- O -- H -- H H     C.sub.2 H.sub.5 -- -- -- OCH.sub.3 CF.sub.3 J.sub.15 -- -- -- O -- H --     CH.sub.3 CH.sub.3 H -- -- -- CH.sub.3 OCH.sub.3 J.sub.15 -- -- --     SO.sub.2 -- H -- H H H -- -- -- CH.sub.3 CH.sub.3 J.sub.15 -- -- --     SO.sub.2 -- H -- H H H -- -- -- CH.sub.3 OCH.sub.3 J.sub.15 -- -- --     SO.sub.2 -- H -- H H H -- -- -- OCH.sub.3 OCH.sub.3 J.sub.15 -- -- -- O     -- H -- CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3 OCH.sub.3 J.sub.15 -- --     -- O -- H -- CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3 CH.sub.3 J.sub.15 --     -- -- O -- H -- CH.sub.3 H CH.sub.3 -- -- -- CH.sub.3 CH.sub.3 J.sub.15     -- -- -- O -- H -- CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3 C.sub.2     H.sub.5 J.sub.15 -- -- -- O -- H -- CH.sub.3 H CH.sub.3 -- -- --     CH.sub.3 OC.sub.2 H.sub.5 J.sub.15 -- -- -- O -- H -- CH.sub.3 H     CH.sub.3 -- -- -- OCH.sub.3 CH.sub.2 OCH.sub.3 J.sub.15 -- -- -- O -- H     -- CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3 CH.sub.2 F J.sub.15 -- -- -- O     -- H -- CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3 CF.sub.3 J.sub.15 -- --     -- S -- H -- CH.sub.3 H H -- -- -- OCH.sub.3 OCH.sub.3 J.sub.15 -- -- --     S --  H -- CH.sub.3 H H -- -- -- OCH.sub.3 CH.sub.3 J.sub.15 -- -- -- S     -- H -- CH.sub.3 H H -- -- -- CH.sub.3 CH.sub.3 J.sub.15 -- -- -- S -- H     -- H CH.sub.3 CH.sub.3 -- -- -- OCH.sub.3 CH.sub.3 J.sub.15 -- -- --     SO.sub.2 -- H -- H H H -- -- -- CH.sub.3 CH.sub.3 J.sub.15 -- -- --     SO.sub.2 -- H -- H H H -- -- -- CH.sub.3 OCH.sub.3 J.sub.15 -- -- --     SO.sub.2 -- H -- H H H -- -- -- OCH.sub.3 OCH.sub.3 J.sub.15 -- -- --     SO.sub.2 -- H -- CH.sub.3 H H -- -- -- OCH.sub.3 OCH.sub.3 192-194     J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H H -- -- -- OCH.sub.3     CH.sub.3 186-187 J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H H -- --     -- CH.sub.3 CH.sub.3 J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H H --     -- -- OCH.sub.3 C.sub.2 H.sub.5 J.sub.15 -- -- -- SO.sub.2 -- H --     CH.sub.3 H H -- -- -- CH.sub.3 OC.sub.2 H.sub.5 J.sub.15 -- -- --     SO.sub.2 -- H -- CH.sub.3 H H -- -- -- OCH.sub.3 CH.sub.2 OCH.sub.3     J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H H -- -- -- OCH.sub.3     CH.sub.2 F J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H H -- -- --     OCH.sub.3 CF.sub.3 J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 CH.sub.3     H -- -- -- OCH.sub.3 OCH.sub.3 J.sub.15 -- -- -- SO.sub.2 -- H --     CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3 OCH.sub.3 J.sub.15 -- -- --     SO.sub.2 -- H -- CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3 CH.sub.3     J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H CH.sub.3 -- -- -- CH.sub.3     CH.sub.3 J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H CH.sub.3 -- -- --     OCH.sub.3 C.sub.2 H.sub.5 J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H     CH.sub.3 -- -- -- CH.sub.3 OC.sub.2 H.sub.5 J.sub.15 -- -- -- SO.sub.2     -- H --  CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3 CH.sub.2 OCH.sub.3     J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3      CH.sub.2 F J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H CH.sub.3 -- --     -- OCH.sub.3 CF.sub.3 J.sub.15 -- -- -- S -- H -- CH.sub.3 H CH.sub.3 --     -- -- OCH.sub.3 OCH.sub.3 J.sub.15 -- -- -- S -- H -- CH.sub.3 H     CH.sub.3 -- -- -- OCH.sub.3 CH.sub.3 J.sub.15 -- -- -- S -- H --     CH.sub.3 H CH.sub.3 -- -- -- CH.sub.3 CH.sub.3 J.sub.15 -- -- --     SO.sub.2 -- 6-Cl -- CH.sub.3 H H -- -- -- CH.sub.3 CH.sub. 3 J.sub.15 --     -- -- SO.sub.2 -- 6-Cl -- CH.sub.3 H H -- -- -- OCH.sub.3 OCH.sub.3     J.sub.15 -- -- -- O -- 6-Cl -- CH.sub.3 H H -- -- -- CH.sub.3 OCH.sub.3     J.sub.15 -- -- -- O -- 5-Br -- H H CH.sub.3 -- -- -- CH.sub.3 OCH.sub.3     J.sub.15 -- -- -- O -- 6-F -- CH.sub.3 H H -- -- -- CH.sub.3 OCH.sub.3     J.sub.15 -- -- -- O -- 5-CH.sub.3 -- CH.sub.3 H H -- -- -- CH.sub.3     OCH.sub.3 J.sub.15 -- -- -- O -- 6-OCH.sub.3 CH.sub.3 H H -- -- -- --     CH.sub.3 OCH.sub.3 J.sub.15 -- -- -- SO.sub.2 -- 6-Cl -- CH.sub.3 H H --     -- -- CH.sub.3 OCH.sub.3 J.sub. 15 -- -- -- S -- 6-Cl -- CH.sub.3 H H --     -- -- CH.sub.3 OCH.sub.3 J.sub.16 -- CH.sub.2 -- O -- H -- CH.sub.3 H --     -- -- -- CH.sub.3 OCH.sub.3 J.sub.16 -- CH.sub.2 -- S -- H -- H CH.sub.3     -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.16 -- O -- SO.sub.2 -- H --     CH.sub.3 H -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.16 -- O -- SO.sub.2 -- H     -- CH.sub.3 H -- -- -- -- CH.sub.3 CH.sub.3 J.sub.17 -- -- -- -- O H --     CH.sub.3 H -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.17 -- -- -- -- S H --     CH.sub.3 H -- -- -- -- CH.sub.3 OCH.sub. 3 J.sub.17 -- -- -- -- O H --     CH.sub.3 CH.sub.3 -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.17 -- -- -- -- O     H -- H H -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.18 -- CH.sub.2 -- -- -- H     -- H H -- H H -- CH.sub.3 OCH.sub.3 J.sub.18 -- CH.sub.2 -- -- -- H -- H     H -- CH.sub.3 H -- OCH.sub.3 CH.sub.3 J.sub.18 -- O -- -- -- H -- H H --     H CH.sub.3 -- CH.sub.3 OCH.sub.3 J.sub.19 -- -- -- -- -- H -- CH.sub.3     CH.sub.3 -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.19 -- -- -- -- -- H -- H H     -- -- -- -- OCH.sub.3 OCH.sub. 3 J.sub.19 -- -- -- -- -- H -- H H -- --     -- -- OCH.sub.3 CH.sub.3 J.sub.19 -- -- -- -- -- H -- CH.sub.3 CH.sub.3     -- -- -- -- OCH.sub.3 CH.sub.3 J.sub.20 -- CH.sub.2 -- -- -- H -- -- --     -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.20 -- CH.sub.2 -- -- -- H -- -- --     -- -- -- -- OCH.sub.3 CH.sub.3 J.sub.20 -- CH.sub.2 -- -- -- H -- -- --     -- -- -- -- CH.sub.3 CH.sub.3 J.sub.20 -- CH.sub.2 -- -- -- 7-Cl -- --     -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.20 -- O -- -- -- H -- --  -- --     -- -- -- OCH.sub.3 OCH.sub.3 J.sub.20 -- O -- -- -- H -- -- -- -- -- --     -- OCH.sub.3 CH.sub.3 J.sub.20 -- O -- -- -- H -- -- -- -- -- -- --     CH.sub.3 CH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- F     OCH.sub.3 CH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- Cl     OCH.sub.3 CH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- Br     OCH.sub.3 CH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- --     OCH.sub.3 OCH.sub.3 OCH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- --     -- -- -- SCH.sub.3 OCH.sub.3 CH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- --     -- -- -- -- -- -- SO.sub.2 CH.sub.3 OCH.sub.3 CH.sub.3 J.sub.21 --     CH.sub.2 -- -- -- -- -- -- -- -- -- -- CO.sub.2 CH.sub.3 OCH.sub.3     OCH.sub.3 122-122.5 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- --     SO.sub.2 N(CH.sub.3).sub.2 OCH.sub.3 CH.sub.3 J.sub.21 -- CH.sub.2 -- --     -- -- -- -- -- -- -- -- OSO.sub.2 CH.sub.3 OCH.sub.3 CH.sub.3 J.sub.21     -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- Cl OCH.sub. 3 CF.sub.3     J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- Cl CH.sub.3 OCH.sub.2     H.sub.5 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- Cl OCH.sub.3     C.sub.2 H.sub.5 J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- F OCH.sub.3     CH.sub.3 J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- Cl OCH.sub.3     CH.sub.3 J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- Br OCH.sub.3     CH.sub.3 J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.3     CH.sub.3 J.sub.21 -- O -- -- --  -- -- -- -- -- -- -- SCH.sub.3 OCH.sub.3      CH.sub.3 J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- SO.sub.2 CH.sub.3     OCH.sub.3 CH.sub.3 J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- CO.sub.2     CH.sub.3 OCH.sub.3 CH.sub.3 J.sub.21 -- O -- -- -- -- -- -- -- -- -- --     SO.sub.2 N(CH.sub.3).sub.2 OCH.sub.3 CH.sub.3 J.sub.21 -- O -- -- -- --     -- -- -- -- -- -- OSO.sub.2 CH.sub.3 OCH.sub.3 CH.sub.3 J.sub.21 --     CH.sub.2 -- -- -- -- -- -- -- -- -- -- CO.sub.2 CH.sub.3 OCH.sub.3     CH.sub.3 187-190 J.sub.21 -- CH.sub.2 -- --  -- -- -- -- -- -- -- --     CO.sub.2 CH.sub.3 CH.sub.3 OC.sub.2 H.sub.5 J.sub.21 -- CH.sub.2 -- --     -- -- -- -- -- -- -- -- CO.sub.2 CH.sub.3 OCH.sub.3 CF.sub.3 J.sub.21 --     CH.sub.2 -- -- -- -- -- -- -- -- -- -- CO.sub.2 CH.sub.3 OCH.sub.3     C.sub.2 H.sub.5 J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- --     OCH.sub.3 CH(CH.sub.3).sub.2 J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 --     -- -- -- -- -- OCH.sub.2 CF.sub.3 OCH.sub.3 J.sub.2 0 CH.sub.2 -- -- --     H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 cyclopropyl J.sub.2 0 CH.sub.2 --     -- --  H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 NHCH.sub.3 J.sub.2 0     CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 N(CH.sub.3).sub.     2 J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3     OCH.sub.2 CH═CH.sub.2 J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- --     -- -- -- -- OCH.sub.3 CH(OCH.sub.3).sub.2 J.sub.2 0 CH.sub.2 -- -- -- H     CH.sub.3 -- -- -- -- -- -- OCH.sub.3 1,3-dioxolan-                2-yl     J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3     CH(OC.sub.2 H.sub.5).sub.2 J.sub.2 0 CH.sub. 2 -- -- -- H CH.sub.3 -- --     -- -- -- -- OCH.sub.3 C.tbd.CH J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 --     -- -- -- -- -- OCH.sub.3 OCH.sub.2 CH.sub.2 OCH.sub.3 J.sub.2 0 CH.sub.2     -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 SCH.sub.3 J.sub.3 0     CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 NHCH.sub.3     J.sub.3 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCF.sub.2 H     OCH.sub.3 J.sub.3 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- --     OCH.sub.3 cyclopropyl J.sub.3 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- --     -- -- OCH.sub.3 CH(OCH.sub.3).sub.2 J.sub.3 0 CH.sub.2 -- -- -- H     CH.sub.3 -- -- -- -- -- -- OCH.sub.3 C.tbd.CH J.sub.3 0 CH.sub.2 -- --     -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 OCH.sub.2 CH.sub.2 OCH.sub.3     J.sub.3 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- CH.sub.3     1,3-dioxolan-                2-yl J.sub.3 0 CH.sub.2 -- -- -- H CH.sub.3     -- -- -- -- -- -- CH.sub.3 OCH.sub.2 C.tbd.CH J.sub.4 0 CH.sub.2 -- --     -- H -- H H -- -- -- -- OCH.sub.3 CH.sub.2 CH.sub.2 CH.sub.3 J.sub.4 0     CH.sub.2 -- -- -- H -- H H -- -- -- -- OCH.sub.3 cyclopropyl J.sub.4 0     CH.sub.2 -- -- -- H -- H H -- -- -- -- OCH.sub.3 C.tbd.CH J.sub.4 0     CH.sub.2 -- -- -- H -- H H -- -- -- -- OCH.sub.3 OCH.sub.2      CH═CH.sub.2 J.sub.4 0 CH.sub.2 -- -- -- H -- H H -- -- -- --     OCH.sub.3 OCH.sub.2 CH.sub.2 F J.sub.5 0 -- -- -- -- H CH.sub.3 -- -- --     -- -- -- OCH.sub.3 CH(CH.sub.3).sub.2 J.sub.5 0 -- -- -- -- H CH.sub.3     -- -- -- -- -- -- OCH.sub.3 cyclopropyl J.sub.5 0 -- -- -- -- H CH.sub.3     -- -- -- -- -- -- OCH.sub.3 C.tbd.CH J.sub.5 0 -- -- -- -- H CH.sub.3 --     -- -- -- -- -- OCH.sub.3 OCH.sub.2 C.tbd.CH J.sub.5 0 -- -- -- -- H     CH.sub.3 -- -- -- -- -- -- OCH.sub.3 OCH.sub.2 CH.sub.2 F J.sub.5 0 --     -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 SCH.sub.3 J.sub.5 0 --     -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 CH(OCH.sub.3).sub.2     J.sub.5 0 -- -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 1,3-dioxolan     -                2-yl J.sub.6 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- --     -- -- OCH.sub.3 CH(CH.sub.3).sub.2 J.sub.6 0 CH.sub.2 -- -- -- H     CH.sub.3 -- -- -- -- -- -- OCH.sub.3 cyclopropyl J.sub.6 0 CH.sub.2 --     -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 C.tbd.CH J.sub.6 0 CH.sub.2     -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 OCH.sub.2 CH.sub.2 F     J.sub.6 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3     SCH.sub.3 J.sub.6 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- --     OCH.sub.3 CH(OCH.sub.3).sub.2 J.sub.8 -- CH.sub.2 -- -- -- H -- -- -- --     -- -- -- OCH.sub.3 NHCH.sub.3 J.sub.8 -- CH.sub.2 -- -- -- H -- -- --     -- -- -- -- OCH.sub.3 C.tbd.CH J.sub.8 -- CH.sub.2 -- -- -- H -- -- --     -- -- -- -- OCH.sub.3 NHCH.sub.3 J.sub.8 -- CH.sub.2 -- -- -- H -- -- --     -- -- -- -- OCH.sub.3 CH(OCH.sub.3).sub.2 J.sub.8 -- CH.sub.2 -- -- -- H     -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.2 C.tbd.CH J.sub.8 -- CH.sub.2 --     -- -- H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.2 CH.sub.2 F J.sub.8 --     CH.sub.2 -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 SCH.sub.3 J.sub.8 --     CH.sub.2 -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 1,3-dioxolan-            2-yl J.sub.8 -- CH.sub.2 -- -- -- H -- -- -- -- -- ---- OCH.sub.3     cyclopropyl J.sub.9 -- O -- -- -- H -- -- -- -- -- -- -- OCH.sub.3     CH(OCH.sub.3).sub.2 J.sub.9 -- O -- -- -- H -- -- -- -- -- -- --     OCH.sub.3 N(CH.sub.3).sub.2 J.sub.9 -- O -- -- -- H -- -- -- -- -- -- --     OCH.sub.3 NHCH.sub.3 J.sub.10 -- -- -- -- -- H CH.sub.3 -- -- -- -- --     -- OCH.sub.3 NHCH.sub.3 J.sub.10 -- -- -- -- -- H CH.sub.3 -- -- -- --     -- -- CH.sub. 3 CH(OCH.sub.3).sub.2 J.sub.11 -- -- -- -- -- H CH.sub.3     -- -- -- -- -- -- OCH.sub.3 CH(OCH.sub.3).sub.2 J.sub.11 -- -- -- -- --     H -- -- -- -- -- -- -- OCH.sub.3 NHCH.sub.3 J.sub.12 -- O -- -- -- H --     -- -- -- -- -- -- CH.sub.3 NHCH.sub.3 J.sub.12 -- O -- -- -- H -- -- --     -- -- -- -- OCH.sub.3 N(CH.sub.3).sub.2 J.sub.12 -- O -- -- -- H -- --     -- -- -- -- -- OCH.sub.3 1,3-dioxolan-                2-yl J.sub.13 --     CH.sub.2 CH.sub.2 -- -- H -- -- -- -- -- --  -- OCH.sub.3 NHCH.sub.3     J.sub.13 -- CH.sub.2 CH.sub.2 -- -- H -- -- -- -- -- -- -- OCH.sub.3     SCH.sub.3 J.sub.13 -- CH.sub.2 CH.sub.2 -- -- H -- -- -- -- -- -- --     OCH.sub.3 CH(OCH.sub.3).sub.2 J.sub.13 -- CH.sub.2 CH.sub.2 -- -- H --     -- -- -- -- -- -- OCH.sub.3 OCH.sub.2 CH.tbd.CH J.sub.14 -- CH.sub.2 --     -- -- H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.2 CH═CH.sub.2     J.sub.14 -- CH.sub.2 -- -- -- H -- -- -- -- -- -- -- CH.sub.3 OCH.sub.2     CH.sub.2 F J.sub.14 -- CH.sub.2 -- -- -- H -- -- -- -- -- -- -- OCH.sub.     2 CF.sub.3 OCH.sub.3 J.sub.14 -- CH.sub.2 -- -- -- H -- -- -- -- -- --     -- OCH.sub.3 OCH.sub.2 CH.sub.2 OCH.sub.3 J.sub.15 -- -- -- O -- H --     CH.sub.3 H H -- -- -- OCH.sub.3 NHCH.sub.3 J.sub.15 -- -- -- O -- H --     CH.sub.3 H H -- -- -- OCH.sub.3 OCH.sub.2 CH═CH.sub.2 J.sub.15 -- --     -- O -- H -- H H H -- -- -- OCH.sub.3 C.tbd.CH J.sub.15 -- -- -- O -- H     -- H H H -- -- -- OCH.sub.3 OCH.sub.2 CH.sub.2 F J.sub.15 -- -- -- O --     H -- CH.sub.3 H H -- -- -- OCH.sub.3 OCH.sub.2 CH═CHCl J.sub.15 --     -- -- O -- H -- H H H -- -- -- CH.sub.3 NHCH.sub.3 J.sub.15 -- -- -- O     -- H -- H H CH.sub.3 -- -- -- OCH.sub.3 N(CH.sub.3).sub.2 J.sub.15 -- --     -- O -- H -- H H CH.sub.3 -- -- -- OCH.sub.3 cyclopropyl J.sub.15 -- --     -- O -- H -- H H CH.sub.3 -- -- -- OCH.sub.3 CH(OCH.sub.3).sub.2     J.sub.15 -- -- -- O -- H -- CH.sub.3 CH.sub.3 H -- -- -- OCH.sub.3     NHCH.sub.3 J.sub.15 -- -- -- O -- H -- CH.sub.3 CH.sub.3 H -- -- --     OCH.sub.3 CH(OCH.sub.3).sub.2 J.sub.15 -- -- -- O -- H -- CH.sub.3 H H     -- -- -- OCH.sub.3 OCH.sub.2 C.tbd.CH J.sub.15 -- -- -- O --  H --     CH.sub.3 CH.sub.3 H -- -- -- OCH.sub.3 SCH.sub.3 J.sub.15 -- -- -- S --     H -- CH.sub.3 H H -- -- -- OCH.sub.3 NHCH.sub.3 J.sub.15 -- -- -- S -- H     -- CH.sub.3 H H -- -- -- OCH.sub.3 N(CH.sub.3).sub.2 J.sub.15 -- -- -- S     -- H -- CH.sub.3 H H -- -- -- OCH.sub.3 OCH.sub.2 CH═CH.sub.2     J.sub.15 -- -- -- S -- H -- CH.sub.3 H H -- -- -- OCH.sub.3 cyclopropyl     J.sub.15 -- -- -- S -- H -- CH.sub.3 H H -- -- -- OCH.sub.3 N(CH.sub.3).s     ub.2 J.sub.15 -- -- -- S -- H -- CH.sub.3 CH.sub.3 CH.sub.3 -- -- --     OCH.sub.3 CH(OCH.sub.3).sub.2 J.sub.15 --  -- -- SO.sub.2 -- H --     CH.sub.3 H H -- -- -- OCH.sub.3 NHCH.sub.3 J.sub.15 -- -- -- SO.sub.2 --     H -- CH.sub.3 H H -- -- -- OCH.sub.3 N(CH.sub.3).sub.2 J.sub.15 -- -- --     SO.sub.2 -- H -- CH.sub.3 H H -- -- -- OCH.sub.3 OCH.sub.2      CH═CH.sub.2 J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H H -- --     -- CH.sub.3 OCH.sub.2 CH.sub.2 OCH.sub.3 J.sub.15 -- -- -- SO.sub.2 -- H     -- CH.sub.3 H H -- -- -- CH.sub.3 CH(OCH.sub.3).sub.2 J.sub.16 --     CH.sub.2 -- O -- H -- CH.sub.3 H -- -- -- -- OCH.sub.3 N(CH.sub.3).sub.2     J.sub.16 -- CH.sub.2 -- S -- H -- H CH.sub.3 -- -- -- -- OCH.sub.3     OCH.sub.2 CH═CH.sub.2 J.sub.16 -- O -- SO.sub.2 -- H -- CH.sub.3 H     -- -- -- -- OCH.sub.3 OCH.sub.2 CH.sub.2 F J.sub.16 -- O -- SO.sub.2 --     H -- CH.sub.3 H -- -- -- -- OCH.sub.3 OCH.sub.2 CH.sub.2 OCH.sub.3     J.sub.17 -- -- -- -- O H -- CH.sub.3 H -- -- -- -- OCH.sub.3 N(CH.sub.3).     sub.2 J.sub.17 -- -- -- -- O H -- CH.sub.3 H -- -- -- -- CH.sub.3     CH(OCH.sub.3).sub.2 J.sub.17 -- -- -- -- S H -- CH.sub.3 H -- -- -- --     OCH.sub.3 NHCH.sub.3 J.sub.18 -- CH.sub.2 -- -- -- H -- H H -- H H --     OCH.sub.3 NHCH.sub.3 J.sub.18 -- CH.sub.2 -- -- -- H -- H H -- CH.sub.3     H OCH.sub.3 N(CH.sub.3).sub.2 J.sub.18 -- O -- -- -- H -- H H -- H     CH.sub.3 -- CH.sub.3 OCH.sub.2 CH.sub.2 OCH.sub.3 J.sub.19 -- -- -- --     -- H -- H H -- -- -- -- CH.sub.3 OCH.sub.2 CH.sub.2 F J.sub.19 -- -- --     -- -- H -- CH.sub.3 CH.sub.3 -- -- -- -- OCH.sub.3 NHCH.sub.3 J.sub.19     -- -- -- -- -- H -- H CH.sub.3 -- -- -- -- OCH.sub.3 C.tbd.CH J.sub.20     -- CH.sub.2 -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 NHCH.sub.3     J.sub.20 -- CH.sub.2 -- -- -- H -- -- -- -- -- -- -- CH.sub.3 OCH.sub.2     CH.sub.2 F J.sub.20 -- O -- -- -- H -- -- -- -- -- -- -- OCH.sub.3     C.tbd.CH J.sub.20 -- O -- -- -- H -- -- -- -- -- -- -- OCH.sub.3     CH(OCH.sub.3).sub.2 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- --     Cl OCH.sub.3 NHCH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- --     -- Br OCH.sub.3 N(CH.sub.3).sub.2 J.sub.21 -- CH.sub.2 -- -- -- -- -- --     -- -- -- -- F OCH.sub.3 NHCH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- -- --     -- -- -- -- -- OCH.sub.3 OCH.sub.3 NHCH.sub.3 J.sub.21 -- CH.sub.2 -- --     -- -- -- -- -- -- -- -- SO.sub.2 N(CH.sub.3).sub.2 OCH.sub.3 C.tbd.CH     J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- Cl OCH.sub.3 OCH.sub.2      CH.sub.2 F J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- Cl OCH.sub.3     NHCH.sub.3 J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- Br OCH.sub.3     NHCH.sub.3 J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- OCH.sub.3     OCH.sub.3 NHCH.sub.3 J.sub.21 -- O -- -- -- -- -- -- -- -- -- --     SO.sub.2 N(CH.sub.3).sub.2 OCH.sub.3 NHCH.sub.3 J.sub.21 -- O -- -- --     -- -- -- -- -- -- -- SO.sub.2      CH.sub.3 OCH.sub.3 NHCH.sub.3

                                      TABLE 3                                     __________________________________________________________________________    General Formula 3                                                                                                               m.p.                        J n L  Q  Q.sub.1                                                                          Q.sub.2                                                                         R.sub.1                                                                         R.sub.2                                                                          R.sub.3                                                                          R.sub.4                                                                         R.sub.5                                                                         R.sub.6                                                                          R.sub.7                                                                         R.sub.8                                                                              R.sub.9                                                                          X.sub.1                                                                            Y.sub.1                                                                          (°C.)                __________________________________________________________________________    J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCH.sub.3                                                                          O                              J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         CH.sub.3                                                                           O                              J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCH.sub.3                                                                          CH.sub.2                       J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OC.sub.2 H.sub.5                                                                   O                              J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCF.sub.2 H                                                                        O                              J.sub.1                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCH.sub.3                                                                          CH.sub.2                       J.sub.1                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         CH.sub.3                                                                           O                              J.sub.1                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCF.sub.2 H                                                                        O                              J.sub.2                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.2                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           O                              J.sub.2                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.2                       J.sub.2                                                                         0 O  -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCF.sub.2 H                                                                        O                              J.sub.2                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.2                       J.sub.2                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           O                              J.sub.2                                                                         1 O  -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.3                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.3                                                                         0 CH.sub. 2                                                                        -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           O                              J.sub.3                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.2                                                                          CH.sub.2                       J.sub.3                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCF.sub.2 H                                                                        O                              J.sub.3                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.3                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.2                       J.sub.3                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OC.sub.2 H.sub.5                                                                   O                              J.sub.3                                                                         1 O  -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.4                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.2                       J.sub.4                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.4                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           O                              J.sub.5                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.2                       J.sub.5                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.5                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           O                              J.sub.6                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.2                       J.sub.7                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCH.sub.3                                                                          CH.sub.2                       J.sub.7                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         CH.sub.3                                                                           O                              J.sub.8                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.8                                                                         --                                                                              O  -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           O                              J.sub.9                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.2                       J.sub.10                                                                        --                                                                              -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.2                       J.sub.10                                                                        --                                                                              -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.11                                                                        --                                                                              -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.12                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.2                       J.sub.12                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.12                                                                        --                                                                              O  -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           O                              J.sub.12                                                                        --                                                                              O  -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.2                       J.sub.13                                                                        --                                                                              CH.sub.2                                                                         O  -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.2                       J.sub.13                                                                        --                                                                              O  O  -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           O                              J.sub.13                                                                        --                                                                              CH.sub.2                                                                         CH.sub.2                                                                         -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.14                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.14                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           O                              J.sub.14                                                                        --                                                                              O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.2                       J.sub.15                                                                        --                                                                              -- -- O  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.15                                                                        --                                                                              -- -- O  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.2                       J.sub.15                                                                        --                                                                              -- -- O  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- CH.sub.3                                                                           O                              J.sub.15                                                                        --                                                                              -- -- S  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.15                                                                        --                                                                              -- -- S  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- CH.sub.3                                                                           O                              J.sub.15                                                                        --                                                                              -- -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.15                                                                        --                                                                              -- -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.2                       J.sub.16                                                                        --                                                                              CH.sub.2                                                                         -- O  --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.2                       J.sub.16                                                                        --                                                                              CH.sub.2                                                                         -- S  --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.16                                                                        --                                                                              CH.sub.2                                                                         -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.16                                                                        --                                                                              O  -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           O                              J.sub.17                                                                        --                                                                              -- -- -- O H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.17                                                                        --                                                                              -- -- -- S H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.18                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              H  H --     -- OCH.sub.3                                                                          O                              J.sub.18                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              CH.sub.3                                                                         --                                                                              --     CH.sub.3                                                                         O                                   J.sub.19                                                                        --                                                                              -- -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.19                                                                        --                                                                              -- -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           O                              J.sub.20                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           O                              J.sub.20                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.20                                                                        --                                                                              O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     OCH.sub.3                                                                        CH.sub.2                            J.sub.20                                                                        --                                                                              O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     OCH.sub.3                                                                        O                                   J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Cl     -- OCH.sub.3                                                                          O                              J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              F      -- OCH.sub.3                                                                          O                              J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Br     -- OCH.sub.3                                                                          O                              J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                                                                          O                              J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              OSO.sub.2 CH.sub.3                                                                   -- OCH.sub.3                                                                          CH.sub.2                       J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 N(CH.sub.3).sub.2                                                           -- OCH.sub.3                                                                          CH.sub.2                       J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              CO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                                                                          CH.sub.2                       J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Cl     -- OCH.sub.3                                                                          O                              J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              F      -- OCH.sub.3                                                                          O                              J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Br     -- OCH.sub.3                                                                          O                              J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                                                                          O                              J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              OSO.sub.2 CH.sub.3                                                                   -- OCH.sub.3                                                                          O                              J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 N(CH.sub.3).sub.2                                                           -- OCH.sub.3                                                                          O                              J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              CO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                                                                          O                              __________________________________________________________________________

                                      TABLE 4                                     __________________________________________________________________________    General Formula 4                                                                                                            m.p.                           J n L  Q  Q.sub.1                                                                          Q.sub.2                                                                         R.sub.1                                                                         R.sub.2                                                                          R.sub.3                                                                          R.sub.4                                                                         R.sub.5                                                                         R.sub.6                                                                          R.sub.7                                                                         R.sub.8                                                                              R.sub.9                                                                          X.sub.1                                                                            (°C.)                   __________________________________________________________________________    J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         CH.sub.3                            J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCH.sub.3                           J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OC.sub.2 H.sub.5                    J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCF.sub.2 H                         J.sub.1                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         CH.sub.3                            J.sub.1                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCH.sub.3                           J.sub.1                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCF.sub.2 H                         J.sub.2                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.2                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.2                                                                         0 O  -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.2                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.2                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OC.sub.2 H.sub.5                    J.sub.2                                                                         1 O  -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.3                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.3                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.3                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OC.sub.2 H.sub.5                    J.sub.3                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.3                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.3                                                                         1 O  -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.4                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.4                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.4                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.5                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.5                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub. 3                          J.sub.5                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OC.sub.2 H.sub.5                    J.sub.6                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCF.sub.2 H                         J.sub.7                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCH.sub.3                           J.sub.7                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         CH.sub.3                            J.sub.8                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.8                                                                         --                                                                              O  -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.9                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.10                                                                        --                                                                              -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.10                                                                        --                                                                              -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.11                                                                        --                                                                              -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OC.sub.2 H.sub.5                    J.sub.12                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.12                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.12                                                                        --                                                                              O  -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.12                                                                        --                                                                              O  -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- OCF.sub.2 H                         J.sub.12                                                                        --                                                                              O  -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.13                                                                        --                                                                              CH.sub.2                                                                         O  -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.13                                                                        --                                                                              O  O  -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OC.sub.2 H.sub.5                    J.sub.13                                                                        --                                                                              CH.sub.2                                                                         CH.sub.2                                                                         -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.14                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.14                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.14                                                                        --                                                                              O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.15                                                                        --                                                                              -- -- O  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                           J.sub.15                                                                        --                                                                              -- -- O  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- CH.sub.3                            J.sub.15                                                                        --                                                                              -- -- O  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCHF.sub.2                          J.sub.15                                                                        --                                                                              -- -- S  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- CH.sub.3                            J.sub.15                                                                        --                                                                              -- -- S  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                           J.sub.15                                                                        --                                                                              -- -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- CH.sub.3                            J.sub.15                                                                        --                                                                              -- -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                           J.sub.16                                                                        --                                                                              CH.sub.2                                                                         -- O  --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.16                                                                        --                                                                              CH.sub.2                                                                         -- S  --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.16                                                                        --                                                                              CH.sub.2                                                                         -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.16                                                                        --                                                                              O  -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              13     -- OCH.sub.3                           J.sub.17                                                                        --                                                                              -- -- -- O H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.17                                                                        --                                                                              -- -- -- S H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.18                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              CH.sub.3                                                                         H --     -- CH.sub.3                            J.sub.18                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              H  H --     -- OCH.sub.3                           J.sub.19                                                                        --                                                                              -- -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.19                                                                        --                                                                              -- -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.2 H.sub.5                   J.sub.20                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.20                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OC.sub.2 H.sub.5                    J.sub.20                                                                        --                                                                              O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.20                                                                        --                                                                              o  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OC.sub.2 H.sub.5                    J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Cl     -- OCH.sub.3                           J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              F      -- OCH.sub.3                           J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              --     Br OCH.sub.3                           J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                           J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              OSO.sub.2 CH.sub.3                                                                   -- OCH.sub.3                           J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 N(CH.sub.3).sub.2                                                           -- OCH.sub.3                           J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              CO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                           J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Cl     -- OCH.sub.3                           J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              F      -- OCH.sub.3                           J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Br     -- OCH.sub.3                           J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                           J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              OSO.sub.2 CH.sub.3                                                                   -- OCH.sub.3                           J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 N(CH.sub.3).sub.2                                                           -- OCH.sub.3                           J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              CO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                           __________________________________________________________________________

                                      TABLE 5                                     __________________________________________________________________________    General Formula 5                                                                                                              m.p.                         J n L  Q  Q.sub.1                                                                          Q.sub.2                                                                         R.sub.1                                                                         R.sub.2                                                                          R.sub.3                                                                          R.sub.4                                                                         R.sub.5                                                                         R.sub.6                                                                          R.sub.7                                                                         R.sub.8                                                                              R.sub.9                                                                          X.sub.1                                                                           Y.sub.3                                                                          (°C.)                 __________________________________________________________________________    J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCH.sub.3                                                                         CH.sub.3                        J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCH.sub.3                                                                         H                               J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         CH.sub.3                                                                          CH.sub.3                        J.sub.1                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCH.sub.3                                                                         CH.sub.3                        J.sub.1                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCH.sub.3                                                                         H                               J.sub.1                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         CH.sub.3                                                                          CH.sub.3                        J.sub.2                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                         H                               J.sub.2                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OC.sub.2 H.sub.5                                                                  H                               J.sub.2                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                          CH.sub.3                        J.sub.2                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                          H                               J.sub.2                                                                         0 O  -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- --  OCH.sub.3                                                                        H                            J.sub.2                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                         H                               J.sub.2                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                          CH.sub.3                        J.sub.2                                                                         1 O  -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                         CH.sub.3                        J.sub.3                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                         H                               J.sub.3                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                                                                          H                               J.sub.3                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                                                                          CH.sub.3                        J.sub.3                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                                                                          H                               J.sub.3                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                         H                               J.sub.3                                                                         1 O  -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                                                                          H                               J.sub.4                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                         H                               J.sub.4                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                         CH.sub.3                        J.sub.4                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                         H                               J.sub.5                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                         H                               J.sub.5                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OC.sub.2 H.sub.5                                                                  CH.sub.3                        J.sub.6                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                         H                               J.sub.7                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCH.sub.3                                                                         CH.sub.3                        J.sub.7                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCH.sub.3                                                                         H                               J.sub.8                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                         H                               J.sub.8                                                                         --                                                                              O  -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                         CH.sub.3                        J.sub.9                                                                         --                                                                              CH.sub.2                                                                         -- -  --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                         CH.sub.3                        J.sub.10                                                                        --                                                                              -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                         H                               J.sub.10                                                                        --                                                                              -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                          H                               J.sub.11                                                                        --                                                                              -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                         H                               J.sub.12                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                         H                               J.sub.12                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                          H.sub.2                         J.sub.12                                                                        --                                                                              O  -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                         H                               J.sub.12                                                                        --                                                                              O  -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                          H                               J.sub.13                                                                        --                                                                              CH.sub.2                                                                         O  -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                         H                               J.sub.13                                                                        --                                                                              O  O  -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                         H                               J.sub.13                                                                        --                                                                              CH.sub.2                                                                         CH.sub.2                                                                         -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                         H                               J.sub.14                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                         H                               J.sub. 14                                                                       --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                          H                               J.sub.14                                                                        --                                                                              O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                          H                               J.sub.15                                                                        --                                                                              -- -- O  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                                                                         CH.sub.3                        J.sub.15                                                                        --                                                                              -- -- O  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                                                                         H                               J.sub.15                                                                        --                                                                              -- -- S  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                                                                         H                               J.sub.15                                                                        --                                                                              -- -- S  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                                                                         CH.sub.3                        J.sub.15                                                                        --                                                                              -- -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                                                                         H                               J.sub.15                                                                        --                                                                              -- -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                                                                         CH.sub.3                        J.sub.16                                                                        --                                                                              CH.sub.2                                                                         -- O  --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                         H                               J.sub.16                                                                        --                                                                              CH.sub.2                                                                         -- S  --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                         H                               J.sub.16                                                                        --                                                                              CH.sub.2                                                                         -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                         H                               J.sub.16                                                                        --                                                                              O  -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                         H                               J.sub.17                                                                        --                                                                              -- -- -- O H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                         H                               J.sub.17                                                                        --                                                                              -- -- -- S H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                                                                          H                               J.sub.18                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              H  H --     -- OCH.sub.3                                                                         H                               J.sub.18                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              CH.sub.3                                                                         H --     -- OCH.sub.3                                                                         H                               J.sub.19                                                                        --                                                                              -- -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                         H                               J.sub.19                                                                        --                                                                              -- -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                         H                               J.sub.20                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- ----                                                                             --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                         H                               J.sub.20                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- ----                                                                             --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                         CH.sub.3                        J.sub.20                                                                        --                                                                              O  -- -- --                                                                              H -- ----                                                                             --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                         H                               J.sub.20                                                                        --                                                                              O  -- -- --                                                                              H -- ----                                                                             --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                         CH.sub.3                        J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Cl     -- CH.sub.3                                                                          H                               J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              F      -- OCH.sub.3                                                                         H                               J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Br     -- OCH.sub.3                                                                         H                               J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                                                                         H                               J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              OSO.sub.2 CH.sub.3                                                                   -- OCH.sub.3                                                                         H                               J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 N(CH.sub.3).sub.2                                                           -- OCH.sub.3                                                                         H                               J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              CO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                                                                         H                               J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Cl     -- OCH.sub.3                                                                         H                               J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              F      -- OCH.sub.3                                                                         H                               J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Br     -- OCH.sub.3                                                                         H                               J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                                                                         H                               J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              OSO.sub.2 CH.sub.3                                                                   -- OCH.sub.3                                                                         H                               J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 N(CH.sub.3).sub.2                                                           -- OCH.sub.3                                                                         H                               J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              CO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                                                                         H                               __________________________________________________________________________

                                      TABLE 6                                     __________________________________________________________________________    General Formula 6                                                                                                               m.p.                        J n L  Q  Q.sub.1                                                                          Q.sub.2                                                                         R.sub.1                                                                         R.sub.2                                                                          R.sub.3                                                                          R.sub.4                                                                         R.sub.5                                                                         R.sub.6                                                                         R.sub.7                                                                         R.sub.8                                                                              R.sub.9                                                                          X.sub.2                                                                            Y.sub.2                                                                           (°C.)                __________________________________________________________________________    J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              --                                                                              --                                                                              --     CH.sub.3                                                                         CH.sub.3                                                                           OCH.sub.3                       J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              --                                                                              --                                                                              --     CH.sub.3                                                                         C.sub.2 H.sub.5                                                                    OC.sub.2 H.sub.5                J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              --                                                                              --                                                                              --     CH.sub.3                                                                         CH.sub.2 CF.sub.5                                                                  SCH.sub.3                       J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              --                                                                              --                                                                              --     CH.sub.3                                                                         CH.sub.3                                                                           SC.sub.2 H.sub.5                J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              --                                                                              --                                                                              --     CH.sub.3                                                                         C.sub.2 H.sub.5                                                                    OCF.sub.2 H                     J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              --                                                                              --                                                                              --     CH.sub.3                                                                         C.sub.2 H.sub.5                                                                    SCF.sub.2 H                     J.sub.1                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              --                                                                              --                                                                              --     CH.sub.3                                                                         C.sub.2 H.sub.5                                                                    OCH.sub.3                       J.sub.1                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              --                                                                              --                                                                              --     CH.sub.3                                                                         C.sub.2 H.sub.5                                                                    SCH.sub.3                       J.sub.1                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              --                                                                              --                                                                              --     CH.sub.3                                                                         C.sub.2 H.sub.5                                                                    SCF.sub. 2 H                    J.sub.2                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              --                                                                              --                                                                              --     -- CH.sub.2 CF.sub.3                                                                  SCH.sub.3                       J.sub.2                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              --                                                                              --                                                                              --     -- CH.sub.2 CH.sub.3                                                                  SC.sub.2 H.sub.5                J.sub.2                                                                         0 O  -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              --                                                                              --                                                                              --     -- CH.sub.2 CH.sub.3                                                                  SC.sub.2 H.sub.5                J.sub.2                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              --                                                                              --                                                                              --     -- CH.sub.2 CH.sub.3                                                                  SCH.sub.3                       J.sub.2                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              --                                                                              --                                                                              --     -- CH.sub.2 CF.sub.3                                                                  SC.sub.2 H.sub.5                J.sub.2                                                                         1 O  -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              --                                                                              --                                                                              --     -- C.sub.2 H.sub.5                                                                    SCH.sub.3                       J.sub.3                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              --                                                                              --                                                                              --     -- CH.sub.3                                                                           SC.sub.2 H.sub.5                J.sub.3                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              --                                                                              --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                       J.sub.3                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              --                                                                              --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                       J.sub.3                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              --                                                                              --                                                                              --     -- CH.sub.3                                                                           SC.sub.2 H.sub.5                J.sub.3                                                                         1 O  -- -- --                                                                              H -- H  H --                                                                              --                                                                              --                                                                              --     -- CH.sub.3                                                                           SC.sub.2 H.sub.5                J.sub.4                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              --                                                                              --                                                                              --     -- CH.sub. 3                                                                          SCH.sub.3                       J.sub.4                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              --                                                                              --                                                                              --     -- C.sub.2 H.sub.5                                                                    SCH.sub.3                       J.sub.4                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              --                                                                              --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                       J.sub.5                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              --                                                                              --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                       J.sub.5                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              --                                                                              --                                                                              --     -- C.sub.2 H.sub.5                                                                    SCH.sub.3                       J.sub.5                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              --                                                                              --                                                                              --     -- CH.sub.2 CF.sub.3                                                                  SCH.sub.3                       J.sub.6                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              --                                                                              --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                       J.sub.7                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              --                                                                              --                                                                              --     CH.sub.3                                                                         CH.sub.2 CH.sub.3                                                                  SC.sub.2 H.sub.5                J.sub.7                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              --                                                                              --                                                                              --     CH.sub.3                                                                         CH.sub.3                                                                           SC.sub.2 H.sub.5                J.sub.8                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  --                                                                              --                                                                              --                                                                              --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                       J.sub.8                                                                         --                                                                              O  -- -- --                                                                              H -- H  --                                                                              --                                                                              --                                                                              --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                       J.sub.9                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              --                                                                              --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                       J.sub.10                                                                        --                                                                              -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              --                                                                              --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                       J.sub.10                                                                        --                                                                              -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              --                                                                              --                                                                              --     -- C.sub.2 H.sub.5                                                                    SC.sub.2 H.sub.5                J.sub.11                                                                        --                                                                              -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              --                                                                              --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                       J.sub.12                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  --                                                                              --                                                                              --                                                                              --                                                                              --     -- C.sub.2 H.sub.5                                                                    SCH.sub.3                       J.sub.12                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  --                                                                              --                                                                              --                                                                              --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                       J.sub.12                                                                        --                                                                              O  -- -- --                                                                              H -- H  --                                                                              --                                                                              --                                                                              --                                                                              --     -- CH.sub.3                                                                           SC.sub.2 H.sub.5                J.sub.12                                                                        --                                                                              O  -- -- --                                                                              H -- H  --                                                                              --                                                                              --                                                                              --                                                                              --     -- C.sub.2 H.sub.5                                                                    SCH.sub.3                       J.sub.13                                                                        --                                                                              CH.sub.2                                                                         O  -- --                                                                              H -- -- --                                                                              --                                                                              --                                                                              --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                       J.sub.13                                                                        --                                                                              O  O  -- --                                                                              H -- -- --                                                                              --                                                                              --                                                                              --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                       J.sub.13                                                                        --                                                                              CH.sub.2                                                                         CH.sub.2                                                                         -- --                                                                              H -- -- --                                                                              --                                                                              --                                                                              --                                                                              --     -- CH.sub.3                                                                           SC.sub.2 H.sub.5                J.sub.14                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              --                                                                              --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                       J.sub.14                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              --                                                                              --                                                                              --     -- CH.sub.3                                                                           SC.sub.2 H.sub.5                J.sub.14                                                                        --                                                                              O  -- -- --                                                                              H -- -- --                                                                              --                                                                              --                                                                              --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                       J.sub.15                                                                        --                                                                              -- -- O  --                                                                              H -- CH.sub.3                                                                         H H --                                                                              --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                       J.sub.15                                                                        --                                                                              -- -- O  --                                                                              H -- CH.sub.3                                                                         H H --                                                                              --                                                                              --     -- CH.sub.3                                                                           SC.sub.2 H.sub.5                J.sub.15                                                                        --                                                                              -- -- O  --                                                                              H -- CH.sub.3                                                                         H H --                                                                              --                                                                              --     -- C.sub.2 H.sub.5                                                                    SCH.sub.3                       J.sub.15                                                                        --                                                                              -- -- S  --                                                                              H -- CH.sub.3                                                                         H H --                                                                              --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                       J.sub.15                                                                        --                                                                              -- -- S  --                                                                              H -- CH.sub.3                                                                         H H --                                                                              --                                                                              --     -- CH.sub.3                                                                           SC.sub.2 H.sub.5                J.sub.15                                                                        --                                                                              -- -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H H --                                                                              --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                       J.sub.15                                                                        --                                                                              -- -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H H --                                                                              --                                                                              --     -- CH.sub.3                                                                           SC.sub.2 H.sub.5                J.sub.16                                                                        --                                                                              CH.sub.2                                                                         -- O  --                                                                              H -- CH.sub.3                                                                         H --                                                                              --                                                                              --                                                                              --     -- C.sub.2 H.sub.5                                                                    SCH.sub.3                       J.sub.16                                                                        --                                                                              CH.sub.2                                                                         -- S  --                                                                              H -- CH.sub.3                                                                         H --                                                                              --                                                                              --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                       J.sub.16                                                                        --                                                                              CH.sub.2                                                                         -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H --                                                                              --                                                                              --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                       J.sub.16                                                                        --                                                                              O  -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H --                                                                              --                                                                              --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                       J.sub.17                                                                        --                                                                              -- -- -- O H -- H  H --                                                                              --                                                                              --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                       J.sub.17                                                                        --                                                                              -- -- -- S H -- H  H --                                                                              --                                                                              --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                       J.sub.18                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              H H --     -- CH.sub.3                                                                           SCH.sub.3                       J.sub.18                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              CH.sub.3                                                                        H --     -- CH.sub.3                                                                           SCH.sub.3                       J.sub.19                                                                        --                                                                              -- -- -- --                                                                              H -- H  H --                                                                              --                                                                              --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                       J.sub.19                                                                        --                                                                              -- -- -- --                                                                              H -- H  H - --                                                                              --                                                                              --     -- CH.sub.3                                                                           SC.sub.2 H.sub.5                J.sub.20                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              --                                                                              --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                       J.sub.20                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              --                                                                              --                                                                              --     -- CH.sub.3                                                                           SC.sub. 2 H.sub.5               J.sub.20                                                                        --                                                                              O  -- -- --                                                                              H -- -- --                                                                              --                                                                              --                                                                              --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                       J.sub.20                                                                        --                                                                              O  -- -- --                                                                              H -- -- --                                                                              --                                                                              --                                                                              --                                                                              --     -- C.sub.2 H.sub.5                                                                    SCH.sub.3                       J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              --                                                                              --                                                                              Cl     -- CH.sub.3                                                                           SCH.sub.3                       J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              --                                                                              --                                                                              F      -- CH.sub.3                                                                           SCH.sub.3                       J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              --                                                                              --                                                                              Br     -- CH.sub.3                                                                           SCH.sub.3                       J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              --                                                                              --                                                                              SO.sub.2 CH.sub.3                                                                    -- CH.sub.3                                                                           SCH.sub.3                       J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              --                                                                              --                                                                              OSO.sub.2 CH.sub.3                                                                   -- CH.sub.3                                                                           SCH.sub.3                       J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              --                                                                              --                                                                              SO.sub.2 N(CH.sub.3).sub.2                                                           -- CH.sub.3                                                                           SCH.sub.3                       J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              --                                                                              --                                                                              CO.sub.2 CH.sub.3                                                                    -- CH.sub.3                                                                           SCH.sub.3                       J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              --                                                                              --                                                                              Cl     -- CH.sub.3                                                                           SCH.sub.3                       J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              --                                                                              --                                                                              F      -- CH.sub.3                                                                           SCH.sub.3                       J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              --                                                                              --                                                                              Br     -- CH.sub.3                                                                           SCH.sub.3                       J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              --                                                                              --                                                                              SO.sub.2 CH.sub.3                                                                    -- CH.sub.3                                                                           SCH.sub.3                       J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              --                                                                              --                                                                              OSO.sub.2 CH.sub.3                                                                   -- CH.sub.3                                                                           SCH.sub.3                       J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              --                                                                              --                                                                              SO.sub.2 N(CH.sub.3).sub.2                                                           -- CH.sub.3                                                                           SCH.sub.3                       J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              --                                                                              --                                                                              CO.sub.2 CH.sub.3                                                                    -- CH.sub.3                                                                           SCH.sub.3                       __________________________________________________________________________

                                      TABLE 7                                     __________________________________________________________________________    General Formula 7                                                                                                           m.p.                            J n L  Q  Q.sub.1                                                                          Q.sub.2                                                                         R.sub.1                                                                         R.sub.2                                                                          R.sub.3                                                                          R.sub.4                                                                         R.sub.5                                                                         R.sub.6                                                                          R.sub.7                                                                         R.sub.8                                                                              R.sub.9                                                                          X.sub.3                                                                           (°C.)                    __________________________________________________________________________    J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCH.sub.3                           J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         CH.sub.3                            J.sub.1                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         CH.sub.3                            J.sub.1                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCH.sub.3                           J.sub.2                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.2                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.2                                                                         0 O  -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.2                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.2                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.2                                                                         1 O  -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.3                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.3                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.3                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.3                                                                         1 O  -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.4                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.4                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.4                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.5                                                                         0 -- -- -- --                                                                              H CH.sub. 3                                                                        -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.5                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.6                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.7                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         CH.sub.3                            J.sub.7                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCH.sub.3                           J.sub.8                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.8                                                                         --                                                                              O  -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.9                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.10                                                                        --                                                                              -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.10                                                                        --                                                                              -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.11                                                                        --                                                                              -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.12                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.12                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.12                                                                        --                                                                              O  -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.12                                                                        --                                                                              O  -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.13                                                                        --                                                                              CH.sub.2                                                                         O  -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.13                                                                        --                                                                              O  O  -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.13                                                                        --                                                                              CH.sub.2                                                                         CH.sub.2                                                                         -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.14                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.14                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.14                                                                        --                                                                              O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.15                                                                        --                                                                              -- -- O  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                           J.sub.15                                                                        --                                                                              -- -- O  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- CH.sub.3                            J.sub.15                                                                        --                                                                              -- -- S  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- CH.sub.3                            J.sub.15                                                                        --                                                                              -- -- S  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                           J.sub.15                                                                        --                                                                              -- -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- CH.sub.3                            J.sub.15                                                                        --                                                                              -- -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                           J.sub.16                                                                        --                                                                              CH.sub.2                                                                         -- O  --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.16                                                                        --                                                                              CH.sub.2                                                                         -- S  --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.16                                                                        --                                                                              CH.sub.2                                                                         -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.16                                                                        --                                                                              O  -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.17                                                                        --                                                                              -- -- -- O H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.17                                                                        --                                                                              -- -- -- S H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.18                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              H  H --     -- OCH.sub.3                           J.sub.18                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              CH.sub.3                                                                         H --     -- CH.sub.3                            J.sub.19                                                                        --                                                                              -- -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.19                                                                        --                                                                              -- -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.20                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.20                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.20                                                                        --                                                                              O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.20                                                                        --                                                                              O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Cl     -- OCH.sub.3                           J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              F      -- OCH.sub.3                           J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Br     -- OCH.sub.3                           J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                           J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              OSO.sub.2 CH.sub.3                                                                   -- OCH.sub.3                           J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 N(CH.sub.3).sub.2                                                           -- OCH.sub.3                           J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              CO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                           J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Cl     -- OCH.sub.3                           J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              F      -- OCH.sub.3                           J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Br     -- OCH.sub.3                           J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                           J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              OSO.sub.2 CH.sub.3                                                                   -- OCH.sub.3                           J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 N(CH.sub.3).sub.2                                                           -- OCH.sub.3                           J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              CO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                           __________________________________________________________________________

FORMULATIONS

Useful formulations of the compounds of Formula I can be prepared inconventional ways. They include dusts, granules, pellets, solutions,suspensions, emulsions, wettable powders, emulsifiable concentrates andthe like. Many of these may be applied directly. Sprayable formulationscan be extended in suitable media and used at spray volumes of from afew liters to several hundred liters per hectare. High strengthcompositions are primarily used as intermediates for furtherformulation. The formulations, broadly, contain about 0.1% to 99% byweight of active ingredient(s) and at least one of (a) about 0.1% to 20%surfactant(s) and (b) about 1% to 99.9% solid or liquid inertdiluent(s). More specifically, they will contain these ingredients inthe following approximate proportions:

                  TABLE 8                                                         ______________________________________                                                    Active  Weight Percent*                                                       Ingredient                                                                            Diluent(s)                                                                              Surfactant(s)                                   ______________________________________                                        Wettable Powders                                                                            20-90      0-74     1-10                                        Oil Suspensions,                                                                             3-50     40-95     0-15                                        Emulsions, Solutions,                                                         (including Emulsifiable                                                       Concentrates)                                                                 Aqueous Suspension                                                                          10-50     40-48     1-20                                        Dusts          1-25     70-99     0-5                                         Granules and Pellets                                                                        0.1-95      5-99.9  0-15                                        High Strength 90"99      0-10     0-2                                         Compositions                                                                  ______________________________________                                         *Active ingredient plus at least one of a Surfactant or a Diluent equals      100 weight percent.                                                      

Lower or higher levels of active ingredient can, of course, be presentdepending on the intended use and the physical properties of thecompound. Higher ratios of surfactant to active ingredient are sometimesdesirable, and are achieved by incorporation into the formulation or bytank mixing.

Typical solid diluents are described in Watkins, et al., "Handbood ofInsecticide Dust Diluents and Carriers", 2nd Ed., Dorland Books,Caldwell, N.J., but other solids, either mined or manufactured, may beused. The more absorptive diluents are preferred for wettable powdersand the denser ones for dusts. Typical liquid diluents and solvents aredescribed in Marsden, "Solvents Guide," 2nd Ed., Interscience, New York,1950. Solubility under 0.1% is preferred for suspension concentrates;solution concentrates are preferably stable against phase separation at0° C. "McCutcheon's Detergents and Emulsifiers Annual", MC PublishingCorp., Ridgewood, N.J., as well as Sisely and Wood, "Encyclopedia ofSurface Active Agents", Chemical Publishing Co., Inc., New York, 1964,list surfactants and recommended uses. All formulations can containminor amounts of additives to reduce foaming, caking, corrosion,microbiological growth, etc.

The methods of making such compositions are well known. Solutions areprepared by simply mixing the ingredients. Fine solid compositions aremade by blending and, usually, grinding as in a hammer or fluid energymill. Suspensions are prepared by wet milling (see, for example,Littler, U.S. Pat. No. 3,060,084). Granules and pellets may be made byspraying the active material upon preformed granular carriers or byagglomeration techniques. See J. E. Browning, "Agglomeration", ChemicalEngineering, Dec. 4, 1967, pp. 147ff. and "Perry's Chemical Engineer'sHandbook", 5th Ed., McGraw-Hill, New York, 1973, pp. 8-57ff.

For further information regarding the art of formulation, see forexample:

H. M. Loux, U.S. Pat. No. 3,235,361, Feb. 15, 1966, Col. 6, line 16through Col. 7, line 19 and Examples 10 through 41;

R. W. Luckenbaugh, U.S. Pat. No. 3,309,192, Mar. 14, 1967, Col. 5, line43 through Col. 7, line 62 and Examples 8, 12, 15, 39, 41, 52, 53, 58,132, 138-140, 162-164, 166, 167 and 169-182;

H. Gysin and E. Knusli, U.S. Pat. No. 2,891,855, June 23, 1959, Col. 3,line 66 through Col. 5, line 17 and Examples 1-4;

G. C. Klingman, "Weed Control as a Science", John Wiley and Sons, Inc.,New York, 1961, pp. 81-96; and

J. D. Fryer and S. A. Evans, "Weed Control Handbook", 5th Ed., BlackwellScientific Publications, Oxford, 1968, pp. 101-103.

In the following examples, all parts are by weight unless otherwiseindicated.

EXAMPLE 9 Wettable Powder

N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocarbonyl]-2-methyl-benzo[B]thiophene-7-methanesulfonamide-1,1-dioxide:80%

sodium alkylnaphthalenesulfonate: 2%

sodium ligninsulfonate: 2%

synthetic amorphous silica: 3%

kaolinite: 13%

The ingredients are blended, hammer-milled until all the solids areessentially under 50 microns, reblended, and packaged.

EXAMPLE 10 Wettable Powder

N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-2,3-dihydro-2-methyl-benzo[B]thiophene-7-methanesulfonamide-1,1-dioxide:50%

sodium alkylnaphthalenesulfonate: 2%

low viscosity methyl cellulose: 2%

diatomaceous earth: 46%

The ingredients are blended, coarsely hammer-milled and then air-milledto produce particles essentially all below 10 microns in diameter. Theproduct is reblended before packaging.

EXAMPLE 11 Granule

Wettable Powder of Example 10: 5%

attapulgite granules (U.S.S. 20-40 mesh; 0.84-0.42 mm): 95%

A slurry of wettable powder containing 25% solids is sprayed on thesurface of attapulgite granules in a double-cone blender. The granulesare dried and packaged.

EXAMPLE 12 Extruded Pellet

1,3-dihydro-N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocarbonyl]-1-oxo-benzo[c]furan-7-methanesulfonamide:25%

anhydrous sodium sulfate: 10%

crude calcium ligninsulfonate: 5%

sodium alkylnaphthalenesulfonate: 1%

calcium/magnesium bentonite: 59%

The ingredients are blended, hammer-milled and then moistened with about12% water. The mixture is extruded as cylinders about 3 mm diameterwhich are cut to produce pellets about 3 mm long. These may be useddirectly after drying, or the dried pellets may be crushed to pass aU.S.S. No. 20 sieve (0.84 mm openings). The granules held on a U.S.S.No. 40 sieve (0.42 mm openings) may be packaged for use and the finesrecycled.

EXAMPLE 13 Low Strength Granule

1,3-dihydro-N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-1-oxo-benzo[c]furan-7-methanesulfonamide:0.1%

attapulgite granules (U.S.S. 20-40 mesh): 99.9%

The active ingredient is dissolved in a solvent and the solution issprayed upon dedusted granules in a double-cone blender. After sprayingof the solution has been completed, the material is warmed to evaporatethe solvent. The material is allowed to cool and then packaged.

EXAMPLE 14 Granule

1,3-dihydro-N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocarbonyl]-1-oxo-benzo[c]furan-7-methanesulfonamide:80%

wetting agent: 1%

crude ligninsulfonate salt (containing 5-20% of the natural sugars): 10%

attapulgite clay: 9%

The ingredients are blended and milled to pass through a 100 meshscreen. This material is then added to a fluid bed granulator, the airflow is adjusted to gently fluidize the material, and a fine spray ofwater is sprayed onto the fluidized material. The fluidization andspraying are continued until granules of the desired size range aremade. The spraying is stopped, but fluidization is continued, optionallywith heat, until the water content is reduced to the desired level,generally less than 1%. The material is then discharged, screened to thedesired size range, generally 14-100 mesh (1410-149 microns), andpackaged for use.

EXAMPLE 15 Low Strength Granule

1,3-dihydro-N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-1-oxo-benzo[c]furan-7-methanesulfonamide:1%

N,N-dimethylformamide: 9%

attapulgite granules (U.S.S. 20-40 sieve): 90%

The active ingredient is dissolved in the solvent and the solution issprayed upon dedusted granules in a double cone blender. After sprayingof the solution has been completed, the blender is allowed to run for ashort period and then the granules are packaged.

EXAMPLE 16 Aqueous Suspension

N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocarbonyl]-2-methyl-benzo[B]thiophene-7-methanesulfonamide-1,1-dioxide:40%

polyacrylic acid thickener: 0.3%

dodecylphenol polyethylene glycol ether: 0.5%

disodium phosphate: 1%

monosodium phosphate: 0.5%

polyvinyl alcohol: 1.0%

water: 56.7%

The ingredients are blended and ground together in a sand mill toproduce particles essentially all under 5 microns in size.

EXAMPLE 17 Solution

N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-2,3-dihydro-2-methyl-benzo[B]thiophene-7-methanesulfonamide-1,1-dioxide,sodium salt: 5%

water: 95%

The salt is added directly to the water with stirring to produce thesolution, which may then be packaged for use.

EXAMPLE 18 High Strength Concentrate

1,3-dihydro-N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-1-oxo-benzo[c]furan-7-methanesulfonamide:99%

silica aerogel: 0.5%

synthetic amorphous silica: 0.5%

The ingredients are blended and ground in a hammer-mill to produce amaterial essentially all passing a U.S.S. No. 50 screen (0.3 mmopening). The concentrate may be formulated further if necessary.

EXAMPLE 19 Wettable Powder

N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-2,3-dihydro-2-methyl-benzo[B]thiophene-7-methanesulfonamide-1,1-dioxide:90%

dioctyl sodium sulfosuccinate: 0.1%

synthetic fine silica: 9.9%

The ingredients are blended and ground in a hammer-mill to produceparticles essentially all below 100 microns. The material is siftedthrough a U.S.S. No. 50 screen and then packaged.

EXAMPLE 20 Wettable Powder

1,3-dihydro-N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocarbonyl]-1-oxo-benzo[c]furan-7-methanesulfonamide:40%

sodium ligninsulfonate: 20%

montmorillonite clay: 40%

The ingredients are thoroughly blended, coarsely hammer-milled and thenair-milled to produce particles essentially all below 10 microns insize. The material is reblended and then packaged.

EXAMPLE 21 Oil Suspension

N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocarbonyl]-2-methyl-benzo[B]thiophene-7-methanesulfonamide-1,1-dioxide:35%

blend of polyalcohol carboxylic esters and oil soluble petroleumsulfonates: 6%

xylene: 59%

The ingredients are combined and ground together in a sand mill toproduce particles essentially all below 5 microns. The product can beused directly, extended with oils, or emulsified in water.

EXAMPLE 22 Dust

N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocarbonyl]-2-methyl-benzo[B]thiophene-7-methanesulfonamide-1,1-dioxide:10%

attapulgite: 10%

Pyrophyllite: 80%

The active ingredient is blended with attapulgite and then passedthrough a hammer-mill to produce particles substantially all below 200microns. The ground concentrate is then blended with powderedpyrophyllite until homogeneous.

EXAMPLE 23 Oil Suspension

N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-2,3-dihydro-2-methyl-benzo[B]thiophene-7-methanesulfonamide-1,1-dioxide:25%

polyoxyethylene sorbitol hexaoleate: 5%

highly aliphatic hydrocarbon oil: 70%

The ingredients are ground together in a sand mill until the solidparticles have been reduced to under about 5 microns. The resultingthick suspension may be applied directly, but preferably after beingextended with oils or emulsified in water.

EXAMPLE 24 Wettable Powder

1,3-dihydro-N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocarbonyl]-1-oxo-benzo[c]furan-7-methanesulfonamide:20%

sodium alkylnaphthalenesulfonate: 4%

sodium ligninsulfonate: 4%

low viscosity methyl cellulose: 3%

attapulgite: 69%

The ingredients are thoroughly blended. After grinding in a hammer-millto produce particles essentially all below 100 microns, the material isreblended and sifted through a U.S.S. No. 50 sieve (0.3 mm opening) andpackaged.

UTILITY

The compounds of the present invention are active herbicides, havingutility for broad-spectrum pre- and/or post-emergence weed control inareas where complete control of all vegetation is desired, such asaround fuel storage tanks, ammunition depots, industrial storage areas,parking lots, drive-in theaters, billboards, and highway and railroadstructures.

The rates of application for the compounds of the invention aredetermined by a number of factors, including the types of weeds to becontrolled, weather and climate, formulations selected, mode ofapplication, amount of foliage present, etc. In general terms, thesubject compounds should be applied at levels of around 0.05 to 5 kg/ha,the lower rates being suggested for use on lighter soils and/or thosehaving a low organic matter content, or for situations where onlyshort-term persistence is required.

The compounds of the invention may be used in combination with any othercommercial herbicide: examples of which are those of the triazine,triazole, uracil, urea, amide, diphenylether, carbamate and bipyridyliumtypes. The compounds may also be used in combination with mefluidide.

The herbicidal properties of the subject compounds were discovered in anumber of greenhouse tests. The test procedure and results follow.

TEST A

Seeds of crabgrass (Digitaria sp.), barnyardgrass (Echinochloacrusgalli), wild oats (Avena fatua), sicklepod (Cassia obtusifolia),morningglory (Ipomoea sp.), cocklebur (Xanthium sp.), sorghum, corn,soybean, cotton rice, sugar beet, rice, wheat and purple nutsedge(Cyperus rotundus) tubers were planted in a growth medium and treatedpre-emergence with the test compounds dissolved in a non-phytotoxicsolvent. At the same time, these crop and weed species were treated witha soil/foliage application. At the time of treatment, the plants rangedin height from 2 to 18 cm. Treated plants and controls were maintainedin a greenhouse for sixteen days, after which all species were comparedto controls and visually rated for response to treatment. The ratings,summarized in Table A, are based on a numerical scale extending from0=no injury, to 10=complete kill. The accompanying descriptive symbolshave the following meanings:

C=chlorosis or necrosis:

G=growth retardation; and

H=formative effects.

The test compounds are referenced in the table of results as follows:##STR30##

                                      TABLE A                                     __________________________________________________________________________                Cmpd. 1                                                                           Cmpd. 2                                                                           Cmpd. 3                                                                           Cmpd. 4                                                                           Cmpd. 5                                                                           Cmpd. 6                                                                           Cmpd. 7                                                                           Cmpd. 8                                                                           Cmpd. 9                                                                           Cmpd. 10                                                                           Cmpd.                                                                              Cmpd. 12            Rate kg/ha  0.05                                                                              0.05                                                                              0.05                                                                              0.05                                                                              0.05                                                                              0.05                                                                              0.05                                                                              0.05                                                                              0.05                                                                              0.05 0.05 0.05                __________________________________________________________________________    POST-EMERGENCE                                                                Morningglory                                                                              6C,9G                                                                             3C,9G                                                                             3C,6H                                                                             10C 8G  10C 2C,6G                                                                             10C 3C,9G                                                                             3G   9C   10C                 Cocklebur   5C,8G                                                                             5C,9G                                                                             3C,5G                                                                             10C 5G  3C,9G                                                                             3G  10C 2G  3G   2C   5C,9G               Sicklepod   4C,8G                                                                             3C,3H                                                                             2C,3G                                                                             9C  3C,3H                                                                             4C,7H                                                                             2C,5G                                                                             9C  5G  0    2C,7G                                                                              2C,6G               Nutsedge    3C,8G                                                                             2G  2C,3G                                                                             5G  2C,3G                                                                             3G  0   3G  0   0    2G   2C                  Crabgrass   0   0   2C,5G                                                                             3C,8G                                                                             3C,7G                                                                             3G  0   5G  0   0    0    0                   Barnyardgrass                                                                             0   0   3C,6H                                                                             4C,9H                                                                             9C  3C,6G                                                                             3C,8H                                                                             3C,8H                                                                             0   0    0    0                   Wild Oats   0   0   3C,6G                                                                             3C,8G                                                                             9C  2C,4G                                                                             4C,8G                                                                             2C  0   0    0    0                   Wheat       0   0   3C,8G                                                                             6G  10C 3G  9C  9G  0   0    1H   3C,8H               Corn        3C,9H                                                                             1H  3C,9G                                                                             2U,9G                                                                             9C  4C,9H                                                                             4C,9G                                                                             3C,9H                                                                             5C,9G                                                                             3C,8G                                                                              5C,9G                                                                              5C,9G               Soybean     3C,9G                                                                             2C,8G                                                                             3H  9C  4C,9H                                                                             5C,9G                                                                             3C,8H                                                                             9C  0   0    0    0                   Rice        2C,6G                                                                             2G  5C,9G                                                                             6C,9G                                                                             9C  9C  9C  9C  0   0    3G   3C,8H               Sorghum     3C,9H                                                                             2C,9H                                                                             4C,9H                                                                             6C,9H                                                                             9C  5C,9H                                                                             5C,9G                                                                             5C,9G                                                                             3C,6G                                                                             0    5C,9G                                                                              5C,9G               Sugar beet  9C  4C,9G                                                                             3C,4M                                                                             10C 3C,7H                                                                             9C  3C,7G                                                                             5C,9G                                                                             9C  2G   4C,9G                                                                              4C,9G               Cotton      3C,8H                                                                             3C,5G                                                                             0   9C  3C,7H                                                                             5C,9G                                                                             3C,5G                                                                             5C,9G                                                                             2C,3G                                                                             1C   3C,8G                                                                              4C,6G               __________________________________________________________________________    PRE-EMERGENCE                                                                 Morningglory                                                                              8G  2C,3H                                                                             0   9G  3C,5H                                                                             9G  8G  9G  8G  3G   9G   9G                  Cocklebur   2C,5H                                                                             2C,2H                                                                             --  8H  0   5H  2H  8H  2H  3G   --   8H                  Sicklepod   1C,2G                                                                             0   0   2C,7G                                                                             2C  2C,2H                                                                             1C  2C,4G                                                                             5G  4G   2C,7G                                                                              2C                  Nutsedge    2G  0   0   4G  0   0   2C  3G  3G  0    5G   0                   Crabgrass   1C  0   2G  2C,5G                                                                             0   0   0   2C,5G                                                                             4G  3G   0    0                   Barnyardgrass                                                                             0   0   1H  4C,9H                                                                             3C,5G                                                                             0   1H  2C,6G                                                                             0   0    3G   3G                  Wild Oats   0   0   2C,7G                                                                             2C,8H                                                                             8G  2C,3G                                                                             5G  2C,5G                                                                             0   0    3G   5G                  Wheat       4G  3G  2C,8G                                                                             3C,9H                                                                             2C,8H                                                                             2G  2C,9H                                                                             2C,7G                                                                             0   0    4G   8G                  Corn        2C,8H                                                                             0   3C,7H                                                                             2U,9G                                                                             3C,8H                                                                             3C,3G                                                                             2C,8H                                                                             4C,9H                                                                             0   3G   2C,7G                                                                              9G                  Soybean     2C,8H                                                                             0   0   3C,8H                                                                             1C  3C,5H                                                                             2C,2H                                                                             4C,6H                                                                             1H  0    2H   3C,7G               Rice        2C,7G                                                                             2G  3C,8H                                                                             5C,9H                                                                             5C,9H                                                                             7H  5C,9H                                                                             5C,9H                                                                             0   0    2G   2G                  Sorghum     3C,8H                                                                             3C,8H                                                                             3C,9G                                                                             5C,9H                                                                             4C,9H                                                                             3C,7H                                                                             5C,9H                                                                             4C,9G                                                                             0   2G   5G   9G                  Sugar beet  9C  3C,8G                                                                             0   9C  8G  5G  5G  9C  5G  2G   5C,9G                                                                              5C,9G               Cotton      8H  1C  0   9G  2G  5G  5G  3C,7G                                                                             2G  0    8G   8G                  __________________________________________________________________________

TEST B Postemergence

Two round pans (25 cm diameter by 12.5 cm deep) were filled withWoodstown sandy loam soil. One pan was planted with blackgrass(Alpecurus myosuroides), sugar beets, nutsedge (Cyperus rotundus)tubers, crabgrass (Digitaria sanquinalis), sicklepod (Cassiaobtusifolia), teaweed (Sida spinosa), jimsonweed (Datura stramonium),velvetleaf (Abutilon theophrasti), oil seed rape (Brassica napus), andgiant foxtail (Setaria faberii). The other pan was planted with wheat,cotton, rice, corn, soybean, wild oats (Avena fatua), cocklebur (Xantiumpensylvanicum), morningglory (Ipomoea hederacea), johnsongrass (Sorghumhalepense) and barnyardgrass (Echinochloa crusgalli). The plants weregrown for approximately fourteen days, then sprayed post-emergence withthe chemicals dissolved in a non-pyytotoxic solvent.

Preemergence

Two round pans (25 cm diameter by 12.5 cm deep) were filled withWoodstown sandy loam soil. One pan was planted with blackgrass, sugarbeets, nutsedge, crabgrass, sicklepod, teaweed, jimsonweed, velvetleaf,oil seed rape, and giant foxtail. The other pan was planted with wheat,cotton, rice, corn, soybeans, wild oats, cocklebur, morningglory,johnsongrass, and barnyardgrass. The two pans were sprayed pre-emergencewith the chemicals dissolved in a non-phytotoxic solvent.

Treated plants and controls were maintained in the greenhouse for 28days, then all treated plants were compared to controls and visuallyrated for plant response utilizing the rating system as described forTest A.

Response ratings are contained in Table B. The data show the potentialutility of several of the compounds tested for selective weed control incrops such as wheat, soybeans and cotton.

                                      TABLE B                                     __________________________________________________________________________    PRE-EMERGENCE ON                                                              WOODSTOWN SANDY LOAM                                                                                                            Com-                                     Compound 1                                                                           Compound 2                                                                           Compound 4.sup.1                                                                              Compound 5                                                                           pound                                                                              Compound 8             Rate g/ha    62 16                                                                              4 62 16                                                                              4 62   16  4   1  62 16                                                                              4 62 16                                                                              62 16 4                __________________________________________________________________________    POST-EMERGENCE                                                                Corn         3G 0 0 0  0 0 100,70                                                                             100,60                                                                            90,30                                                                             80 80 50                                                                              0 70 40                                                                              100                                                                              90 60               Wheat        0  0 0 0  0 0 0,0  0,0 0,0 0,0                                                                              0  0 0 50 0 70 0  0                Rice         5G 3G                                                                              0 6G 4G                                                                              0 80,0 70,0                                                                              30,0                                                                              0,0                                                                              0  0 0 70 30                                                                              90 30 0                Soybean      9G 6G                                                                              3G                                                                              9G 8G                                                                              5G                                                                              100,90                                                                             100,90                                                                            100,80                                                                            70,20                                                                            90 80                                                                              60                                                                              90 90                                                                              100                                                                              90 90               Cotton       7G 3G                                                                              0 5G 3G                                                                              0 100,50                                                                             100,20                                                                            40,0                                                                              0,0                                                                              60 0 0 0  0 90 20 0                Sugar beet   7G 3G                                                                              0 9G 5G                                                                              0 100,90                                                                             40,90                                                                             0,40                                                                              0,0                                                                              70 60                                                                              30                                                                              80 70                                                                              70 20 0                Rape         -- --                                                                              --                                                                              -- --                                                                              --                                                                              100,100                                                                            100,90                                                                            100,90                                                                            50,40                                                                            100                                                                              90                                                                              60                                                                              90 70                                                                              100                                                                              90 70               Crabgrass    0  0 0 3G 0 0 20,0 0,0 0,0 0,0                                                                              0  0 0 20 0 60 0  0                Johnsongrass 9G 4G                                                                              0 5G 2G                                                                              0 100,90                                                                             100,0                                                                             60,0                                                                              20 0  0 0 20 0 90 90 70               Blackgrass   0  0 0 0  0 0 100,70                                                                             70,0                                                                              30,0                                                                              0,0                                                                              80 0 0 70 0 90 80 20               Barnyardgrass                                                                              3G 0 0 3G 0 0 70,50                                                                              40,0                                                                              0,0 0,0                                                                              0  0 0 0  0 60 20 0                Nutsedge     5G 2G                                                                              0 7G 3G                                                                              0 40,- 30,0                                                                              0,0 0,0                                                                              0  0 0 0  0 0  0  0                Giant Foxtail                                                                              6G 0 0 7G 4G                                                                              0 50,0 0,0 0,0 0,0                                                                              0  0 0 0  0 40 0  0                Wild Oats    0  0 0 0  0 0 30,0 0,0 0,0 0,0                                                                              0  0 0 50 0 40 0  0                Cocklebur    8G 3G                                                                              0 9G 5G                                                                              2G                                                                              100,90                                                                             60,70                                                                             30,0                                                                              0,0                                                                              100                                                                              90                                                                              70                                                                              0  0 80 90 30               Morningglory 9G 8G                                                                              3G                                                                              9G 6G                                                                              3G                                                                              100,90                                                                             40,90                                                                             0,90                                                                              0,50                                                                             100                                                                              90                                                                              80                                                                              90 60                                                                              100                                                                              100                                                                              90               Teaweed      0  0 0 4G 0 0 80,80                                                                              50,80                                                                             30,0                                                                              0,0                                                                              50 20                                                                              0 30 0 90 80 20               Sicklepod    3G 0 0 6G 3G                                                                              0 100,100                                                                            90,90                                                                             30,70                                                                             0,0                                                                              0  0 0 50 0 90 60 20               Jimsonweed   8G 6G                                                                              2G                                                                              8G 4G                                                                              2G                                                                              100,90                                                                             90,90                                                                             60,70                                                                             30,30                                                                            90 80                                                                              0 30 0 80 50 0                Velvetleaf   9G 7G                                                                              3G                                                                              9G 5G                                                                              0 100,100                                                                            100,90                                                                            100,90                                                                            30,50                                                                            80 0 0 70 0 100                                                                              90 40               __________________________________________________________________________    PRE-EMERGENCE                                                                 Rate g/ha    250                                                                              62  250                                                                              62                                                                              16                                                                              250  62  16     250                                                                              62  250                                                                              62                                                                              250                                                                              62 16               __________________________________________________________________________    Corn         2G 0   0  0 0 90,100                                                                             40,30                                                                             0,0    80 0   40 0 50 0  0                Wheat        0  0   2G 0 0 30,30                                                                              0,0 0,0    0  0   0  0 40 0  0                Rice         7G 4G  7G 6G                                                                              6G                                                                              100  90,100                                                                            40,60  80 30  90 70                                                                              100                                                                              90 50               Soybean      3G 0   2C 0 0 80,100                                                                             60,50                                                                             20,0   70 20  40 0 70 0  0                Cotton       7G 2G  0  0 0 40,60                                                                              0,50                                                                              0,0    20 0   20 0 30 0  0                Sugar beet   9G 3G  10G                                                                              8G                                                                              0 90,100                                                                             30,100                                                                            0,50   80 20  80 30                                                                              60 0  0                Rape         -- --  -- --                                                                              --                                                                              100  80,50                                                                             30,0   90 30  60 20                                                                              90 20 0                Crabgrass    9G 5G  9G 8G                                                                              6G                                                                              90,60                                                                              0,30                                                                              0,0    0  0   20 0 60 30 0                Johnsongrass 8G 4G  8G 5G                                                                              0 90,100                                                                             90,90                                                                             80,60  90 80  70 30                                                                              90 90 30               Blackgrass   8G 3G  8G 4G                                                                              0 90,100                                                                             70,80                                                                             0,40   90 80  90 60                                                                              90 80 30               Barnyardgrass                                                                              4G 2G  3G 0 0 90,100                                                                             70,60                                                                             20,20  70 0   0  0 90 50 0                Nutsedge     8G 5G  8G 5G                                                                              2G                                                                              0,0  0,0 0,0    70 20  30 0 20 0  0                Giant Foxtail                                                                              6G 2G  4G 2G                                                                              0 100  70,70                                                                             0,0    70 0   20 0 90 50 0                Wild Oats    0  0   0  0 0 60,40                                                                              30,0                                                                              0,0    0  0   0  0 80 20 0                Cocklebur    8G 0   3G 0 0 80,90                                                                              70,60                                                                             0,40   90 0   0  0 60 0  0                Morningglory 0  0   3G 0 0 90,80                                                                              20,30                                                                             0,0    90 0   0  0 0  0  0                Teaweed      9G 5G  9G 5G                                                                              0 90,90                                                                              50,50                                                                             0,0    60 20  60 0 90 50 20               Sicklepod    10G                                                                              6G  8G 8G                                                                              5G                                                                              70,50                                                                              30,20                                                                             0,0    0  0   50 0 70 20 0                Jimsonweed   8G 6G  9G 6G                                                                              0 90,100                                                                             70,90                                                                             20,30  90 50  50 30                                                                              90 40 0                Velvetleaf   8G 4G  8G 3G                                                                              0 90,100                                                                             70,60                                                                             20,30  50 0   50 30                                                                              80 30 0                __________________________________________________________________________     .sup.1 Note: there are two sets of data for each rate tested.      PG,104

What is claimed is:
 1. A compound of the formula ##STR31## andagriculturally suitable salts thereof, wherein J is ##STR32## n is 0 or1; L is CH₂ or O;Q is CH₂ or O; Q₁ is O, S or SO₂ ; Q₂ is O or S; R is Hor CH₃ ; R₁ is H, F, Cl, Br, CH₃ or OCH₃ ; R₂ is H or C₁ -C₃ alkyl; R₃is H or CH₃ ; R₄ is H or CH₃ ; R₅ is H, CH₃ or C₂ H₅ ; R₆ is H or CH₃ ;R₇ is H or CH₃ ; R₈ is F, Cl, Br, OCH₃, SCH₃, SO₂ CH₃, CO₂ CH₃, SO₂N(CH₃)₂ or OSO₂ CH₃ ; A is ##STR33## X is CH₃, OCH₃, Cl, Br, OCH₂ CF₃ orOCF₂ H; Y is C₁ -C₃ alkyl, CH₂ F, cyclopropyl, C.tbd.CH, OCH₃, OC₂ H₅,CH₂ OCH₃, NH₂, NHCH₃, N(CH₃)₂, OCH₂ CH₂ F, CF₃, SCH₃, OCH₂ CH═CH₂, OCH₂C.tbd.CH, OCH₂ CH₂ OCH₃, CR(OCH₃)₂, ##STR34## CR(OCH₂ CH₃)₂ or OCF₂ H; Zis CH;provided that when X is Cl or Br, then Y is OCH₃, OC₂ H₅, NHCH₃,N(CH₃)₂ or OCF₂ H.
 2. A compound of claim 1 where Y is CH₃, C₂ H₅, OCH₃,OC₂ H₅, CH₂ OCH₃, CH₂ F or CF₃ ; and L is CH₂.
 3. A compound of claim 2where J is J₃, J₈, J₁₅ or J₁₆.
 4. A compound of claim 3 where R is H; R₁is H; and X is CH₃ or OCH₃.
 5. A compound of claim 1 where R is H; X isCH₃ or OCH₃ ; Y is CH₃, C₂ H₅, OCH₃, OC₂ H₅, CH₂ OCH₃, CH₂ F, or CF₃. 6.The compound of claim 1 which is1,3-dihydro-N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-1-oxo-benzo[c]furan-7-methanesulfonamide.7. The compound of claim 1 which isN-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-2,3-dihydro-2-methyl-benzo[B]thiophene-7-methanesulfonamide-1,1-dioxide.8. A composition for the control of undesirable vegetation consistingessentially of a compound of claim 1 and at least one of (a) a surfaceactive agent, and (b) a solid or liquid diluent.
 9. A composition forthe control of undesirable vegetation consisting essentially of acompound of claim 2 and at least one of (a) a surface active agent, and(b) a solid or liquid diluent.
 10. A composition for the control ofundesirable vegetation consisting essentially of a compound of claim 3and at least one of (a) a surface active agent, and (b) a solid orliquid diluent.
 11. A composition for the control of undesirablevegetation consisting essentially of a compound of claim 4 and at leastone of (a) a surface active agent, and (b) a solid or liquid diluent.12. A composition for the control of undesirable vegetation consistingessentially of a compound of claim 5 and at least one of (a) a surfaceactive agent, and (b) a solid or liquid diluent.
 13. A composition forthe control of undesirable vegetation consisting essentially of acompound of claim 6 and at least one of (a) a surface active agent, and(b) a solid or liquid diluent.
 14. A composition for the control ofundesirable vegetation consisting essentially of a compound of claim 7and at least one of (a) a surface active agent, and (b) a solid orliquid diluent.
 15. A method for the control of undesirable vegetationcomprising applying to the locus of such vegetation an herbicidallyeffective amount of a compound of claim
 1. 16. A method for the controlof undesirable vegetation comprising applying to the locus of suchvegetation an herbicidally effective amount of a compound of claim 2.17. A method for the control of undesirable vegetation comprisingapplying to the locus of such vegetation an herbicidally effectiveamount of a compound of claim
 3. 18. A method for the control ofundesirable vegetation comprising applying to the locus of suchvegetation an herbicidally effective amount of a compound of claim 4.19. A method for the control of undesirable vegetation comprisingapplying to the locus of such vegetation an herbicidally effectiveamount of a compound of claim
 5. 20. A method for the control ofundesirable vegetation comprising applying to the locus of suchvegetation an herbicidally effective amount of a compound of claim 6.21. A method for the control of undesirable vegetation comprisingapplying to the locus of such vegetation an herbicidally effectiveamount of a compound of claim 7.